Application of Response Surface Methodology for Statistical Analysis of Treatment of Wastewater from a Para Rubber Plant Using Ozonation
Abstract
One of the major problems of a rubber processing factory is poor wastewater quality that does not fall within the standard set forth by the Department of Industrial Works. The objective of the present research was therefore to study para rubber wastewater treatment using ozonation as well as the application of Response Surface Methodology (RSM) with the Central Composite Design (CCD) model for statistical analysis of the treatment data. The studied factors include the dosage rate of ozone, which was varied at 3 levels, i.e., 600, 900, and 1,200 mg/h; the contact time, which was varied at 3 levels, i.e., 90, 120, and 150 min; and pH, which was again varied at 3 levels, i.e., 3, 7, and 9. From the results, it was found that the highest COD and BOD removal efficiencies were 43.51±1.86 and 83.51±5.82%, respectively. Statistical analysis results reveal that the Quadratic model was the most suitable mathematical model for the prediction of BOD removal efficiency. The value of R2 was equal to 0.9249, while the F-value and p-value were 38.86 and less than 0.0001, respectively, suggesting that the model was significant. The p-value of Lack of Fit was, on the other hand, 0.1451, indicating that the Lack of Fit of the model was insignificant. The optimal condition was noted to be at the ozone dosage rate of 1,200 mg/h, contact time of 126 min and pH of 9; such a condition resulted in the BOD removal efficiency of 85.99%.
References
Satsue, P. and Phitthayaphinant, P., 2019, “Para-rubber Industry under ASEAN Economic Community: Manifestation of Para-rubber Plantation Area in the Large City of Two Sea,” King Mongkut’s Agricultural Journal, 37 (4), pp. 675-685.
Intraskul, S., Somboonsuke, B. and Phitthayaphinant, P., 2017, “Thai Para-rubber Industry: The Status and Development Suggestions towards ASEAN Economic Community,” Humanity and Social Science Journal, Ubon Ratchathani University, 8 (Special Edition), pp. 80-107.
Chinlee, S. and Dachapanya, W., 2022, “COD Removal Efficiency of Pararubber Wastewater by Ozonation using the Central Composite Design Model,” Thai Environmental Engineering Journal, 36 (2), pp. 35-43.
Somboonsukea, B., Wisitpaiboon, S., Muneenamb, U. and Phitthayaphinan, P., 2019, “Problem Solving in Ribbed Smoke Sheet (RSS) Production by Environmentally Friendly Rubber Fund Cooperatives in Songkhla Province,” Kasetsart Journal of Social Sciences, 40, pp. 528-538.
Puetpaiboon, U., Sridang, P., Chevakidagarn, P., Siriwong, J. and Danteravanich, S., 2011, Utilization of Concentrated Latex Wastewater for Land Application in Oil Palm Plantation [Online], Available: https://kb.psu.ac.th/psukb/handle/ 2010/8626. [1 March 2023]
Tuprakay, S.R. and Tuprakay, S., 2015, “Wastewater Treatment from Rubbing Processing by Using Solar Distillation System,” SDU Research Journal Science and Technology, 8 (2), pp. 35-52.
Chokejaroenrat, C. and Sakulthaew, C., 2017, Removing a Potent Natural Hormone (17beta-Estradiol) from Water by Ultraviolet (UV) Light-Activated Persulfate Oxidation [Online], Available: http://sutir.sut.ac.th:8080/ jspui/bitstream/123456789/7184/2/Fulltext. pdf. [26 February 2023]
Dechapanya, W., Nontula, S., Phudthabun, S., Sanongraj, S. and Mattaraj, S., 2022, “Treatment of Gaseous Formaldehyde in a Gross Anatomy Laboratory Using Ozonation,” Ladkrabang Engineering Journal, 39 (1), pp. 11-22.
Loysuangsin, W., 2021, “Treatment of Wastewater from Iso Tank Container Cleaning Processby Using High Pressure Plasma System Ozone,” Journal of Science and Technology, 4 (1), pp.34-45.
Chiaplam, S., Kreetachat, T. and Kreetacha, N., 2018, “Treatment Efficiency of 17 Alpha-Methyltestosterone in Aqueous Solution by Advanced Oxidation Processes,” Thai Environmental Engineering Journal, 32 (1), pp. 51- 60.
Kantacha, A., 2001, Wastewater Treatment by Using Ozone: A Case Study of Wastewater from Samrong Canal [Online], Available: http://kb.tsu.ac.th/jspui/bitstream/ 123456789/595/1/71112.pdf [19 January 2023]
Pollution Control Department, 2010, Procedure for Water Sampling from Pollution Sources [Online], Available: https://www.pcd. go.th/publication/4209 [ 10 September 2022]
Department of Industrial Works, 2017, Announcement of Ministry of Industry: Standards for Effluent Control from Industry [Online], Available: http://reg3.diw.go.th/ diw_info/wp-content/uploads/m.94-9.pdf [23 October 2022]
Rungruang, N. and Babel, S., 2008, “Treatment of Natural Rubber Processing Wastewater by Combination of Ozonation and Activated Sludge Process,” Proceedings of International Conference on Environmental Research and Technology (ICERT 2008), 28-30 May 2008, Parkroyal Penang, Malaysia, , pp. 259-263.
Massoudinejad, M., Rabori, M.M. and Dehghani, M.H., 2015, “Treatment of Natural Rubber Industry Wastewater through a Combination of Physicochemical and Ozonation Processes” Journal of Advances in Environmental Health Research, 3 (4), pp. 242-9. https://doi.org/10.22102/jaehr.2015.40208
Rice, E.W., Baird, R.B., Eaton, A.D. and Clesceri, L.S., 2012, American Public Health Association, American Water Works Association, and Water Environment Federation. 2012. Standard Method for the Examination of Water and Wastewater, 22nd ed., American Public Health Association, Washington D.C., pp. 50-51.
Jantana, Y. and Rattanawai, N., 2022, “Optimizing Factors for Lemongrass Slicer Using Design of Experiment,” Science and Technology Nakhon Sawan Rajabhat University Journal, 14 (19), pp. 83-95.
Dechapanya, W. Taweewut, K. Mungkornkaew, P. and Lakawipat, T., 2019, “Treatment of Para Rubber Wastewater using Fenton Processes,” UBU Engineering Journal, 12 (2), pp. 63-76.
Wongkamchao Y. and Dechapanya, W., 2021, “Optimization of Para Rubber Wastewater Treatment Using Fenton Process by Central Composite Design,” Proceedings of UBRC 15th: Future Trends of Research and Innovation, 22-23 July 2021, Ubon Ratchathani University, Ubonratchathani, pp. 226-235.
Homon, P., Jongsuphanphong, M., Pankrib, T. and Chantawong, P., 2016, “The Development and Design of Wastewater Treatment from Battery Factory by High Pressure Plasma System of Ozone Technology,” The Journal of Applied Science, 15 (1), pp. 1-13.
Somkerd, T.and Suwannawittaya, P., 2019, “The Study of Catalytic Ozonation in Effluent Pulp and Paper Industry,” Proceedings of 57th Kasetsart University Annual Conference: Science and Genetic Engineering, Architecture and Engineering, Agro-Industry, Natural Resources and Environment, 29 January – 1 Febuary 2019, Bangkok, Thailand, pp. 917-924.
Chodok, P., 2017, Optimization of Culture Conditions for Extracellular 5-Aminolevulinic Acid Production by Rhodopseudomonas palustris LBL15 Using Response Surface Methodology,” Burapha Science Journal, 22 (2), pp. 300-316.
Phanyusoh, D., Somnuk, K. and Prateepchaikul, G., 2019, “Optimization of Ethyl Ester Production from Palm Fatty Acid Distillate (PFAD) Using Double-Step Esterification Process: A Response Surface Methodology Approach,” Engineering Journal Chiang Mai University, 26 (1), pp. 107-120.
Kaewploy, S., 2016, “Optimal Parameter in Tempering of Alloy Steels Using Response Surface Methodology,” Thai Industrial Engineering Network Journal, 2 (2), pp. 49-55.
Mueanmas, C., 2022, “Study of Palm Oil Catalytic Cracking on ZSM-5 Zeolite for Production of Organic Liquid Product Using Response Surface Methodology,” Burapha Science Journal, 27 (3), pp. 1911-1929.
Awapak, D., Mahae, N. and Pitchairat, D., 2013, “Optimization of Polysaccharide Extraction from Gracilaria fisheri Using Response Surface Methodology,” KKU Science Journal, 41 (2), pp. 414-430.
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2023 King Mongkut's University of Technology Thonburi

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
Any form of contents contained in an article published in Science and Engineering Connect, including text, equations, formula, tables, figures and other forms of illustrations are copyrights of King Mongkut's University of Technology Thonburi. Reproduction of these contents in any format for commercial purpose requires a prior written consent of the Editor of the Journal.