PREPARATION OF Lu2.5Y0.5(Al5-xGax)O12:Ce TRANSLUCENT CERAMIC FOR X-RAY DETECTION APPLICATIONS USING SPARK PLASMA SINTERING (SPS)

Preparation of Lu2.5Y0.5(Al5-xGax)O12:Ce Translucent Ceramic for X-ray Detection Applications using SPS

Authors

  • Prapon Lertloypanyachai Faculty of Science and Technology, Muban Chombueng Rajabhat University, Ratchaburi 70150, Thailand.
  • Prom Kantuptim Department of Materials Engineering, Faculty of Engineering, Kasetsart University, Bangkok 10900, Thailand.
  • Toshiaki Kunikata Division of Materials Science, Nara Institute of Science and Technology, 8916-5 Ikoma, Nara, 630-0192, Japan.
  • Anuwat Hassadee Program of Physics, Faculty of Education, Bansomdejchaopraya Rajabhat University, Bangkok 10600, Thailand.
  • Weerapong Chewpraditkul Faculty of Science, King Mongkut’s University of Technology Thonburi, Bangkok 10140, Thailand.
  • Takumi Kato Division of Materials Science, Nara Institute of Science and Technology, 8916-5 Ikoma, Nara, 630-0192, Japan.
  • Daisuke Nakauchi Division of Materials Science, Nara Institute of Science and Technology, 8916-5 Ikoma, Nara, 630-0192, Japan.
  • Noriaki Kawaguchi Division of Materials Science, Nara Institute of Science and Technology, 8916-5 Ikoma, Nara, 630-0192, Japan.
  • Takayuki Yanagida Division of Materials Science, Nara Institute of Science and Technology, 8916-5 Ikoma, Nara, 630-0192, Japan.

DOI:

https://doi.org/10.55766/sujst9837

Keywords:

Luminescence, Translucent ceramic, X-ray detection

Abstract

In this research, translucent ceramics of Lu2.5Y0.5(Al5-xGax)O12 doped with Ce 1 mol% were fabricated using a spark plasma sintering (SPS) furnace. The microstructure of translucent ceramic was revealed by a scanning electron microscopy (SEM) technique which indicated grain boundaries as polycrystalline characteristics. The absorption spectra showed the absorption lines of Ce³⁺, with an absorption edge around 480 nm, corresponding to the 4f-5d transitions of the Ce³⁺ ions. The photoluminescence (PL) emission band was presented at approximately 507-535 nm, attributed to the Ce3+: 5d1-4f transition. In addition, PL emission results also showed a slight blue shift with increasing Ga substitutional content in the garnet structure. The radioluminescence (RL) spectra displayed a broad emission band between 450 and 690 nm under X-ray excitation. The PL decay time constants for all samples were on the order of tens of nanoseconds. The increasing Ga content in these ceramic scintillators leads to improvement of luminescence efficiency, luminescence decay time reduction, which is crucial for the development of novel scintillators for X-ray detection applications.

References

Blasse, G. and Grabmaier, B.C. (1994). Luminescent Materials. 1st ed. Springer, Berlin, Heidelberg, Germany, 232p. https://doi.org/10.1007/978-3-642-79017-1.

Dhanaraj, G., Byrappa, K., Prasad, V., and Dudley, M. (2010). Springer Handbook of Crystal Growth. 1st ed. Springer Berlin, Heidelberg, 1818p. https://doi.org/10.1007/978-3-540-74761-1

Dorenbos, P. (2013). Electronic structure and optical properties of the lanthanide activated RE3(Al1-x Gax)5O12 (RE = Gd, Y, Lu) garnet compounds. Journal of Luminescence, 134:310-318. https://doi.org/10.1016/j.jlumin.2012.08.028

Grigorjeva, L., Kamada, K., Nikl, M., Yoshikawa, A., Zazubovich, S., and Zolotarjovs, A. (2018). Effect of Ga content on luminescence and defects formation processes in Gd3(Ga,Al)5O12:Ce single crystals. Optical Materials, 75:331-336. https://doi.org/10.1016/j.optmat.2017.10.054

Haynes, W.M. (2014). Handbook of Chemistry and Physics. 95th ed. CRC Press Taylor & Francis Group, CRC Press, https://doi.org/10.1201/b17118

Koshimizu, M., Yanagida, T., Shinsho, K., Yanagisawa, S., Fujimoto, Y., Yagi, H., Yanagitani, T., and Asai, K. (2018). Similarity of trap state and thermoluminescence processes of Y3Al5O12 (YAG):Ce for X-ray and UV irradiation. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 435:285-289, https://doi.org/10.1016/j.nimb.2018. 06.008.

Lecoq, P., Annenkov, A., Gektin, A., Korzhik, M., and Pedrini, C. (1994). Inorganic Scintillators for Detector Systems. 1st ed. Springer, Berlin, Heidelberg, Germany, 251p. https://doi.org/10.1007/3-540-27768-4

Mori, M., Xu, J., Okada, G., Yanagida, T., Ueda, J., and Tanabe, S. (2016). Scintillation and optical properties of Ce-doped YAGG transparent ceramics. Journal of Rare Earths, 34(8):763-768. https://doi.org/10.1016/S1002-0721(16)60091-1

Napierkowski, A.M., Gieszczyk, W., Mrozik, A., Łukaszek, S.W., Zorenko, T., Bartosiewicz, K., Bilski, P., and Zorenko, Y. (2023). Luminescent properties of Gd1.4Lu0.1Y1.5Al5O12:Ce and Gd3Ga2.7Al2.3O12:Ce single crystals grown by micro-pulling down technique. Journal of Luminescence, 263:120117. https://doi.org/10.1016/j.jlumin.2023.120117

Ogiegło, J.M., Katelnikovas, A., Zych, A., Jüstel, T., Meijerink, A., and Ronda, C.R. (2013). Luminescence and Luminescence Quenching in Gd3(Ga, Al)5O12 Scintillators Doped with Ce3+. Journal of Physical Chemistry A, 117(12):2479-2484. https://doi.org/10.1021/jp309572p

Ronda, C.R. (2007). Luminescence from Theory to Applications. Wiley‐VCH Verlag GmbH & Co. KGaA, Germany, 260p. https://doi.org/10.1002/9783527621064

Ueda, J. and Tanabe, S. (2019). Review of luminescent properties of Ce3+-doped garnet phosphors: New insight into the effect of crystal and electronic structure. Optical Materials: X, 1:100018. https://doi.org/10.1016/j.omx.2019.100018

Ueda, J., Aishima, K., and Tanabe, S. (2013). Temperature and compositional dependence of optical and optoelectronic properties in Ce3+-doped Y3Sc2Al3xGaxO12 (x = 0, 1, 2, 3). Optical Materials, 35(11):1952-1957.

http://dx.doi.org/10.1016/j.optmat.2012.11.016

Ueda, J., Tanabe, S., and Nakanishi, T. (2011). Analysis of Ce3+ luminescence quenching in solid solutions between Y3Al5O12 and Y3Ga5O12 by temperature dependence of photoconductivity measurement. Journal of Applied Physics, 110:053102. https://doi.org/10.1063/1.3632069

Wallace, S.K. and McKenna, K.P. (2014). Grain boundary controlled electron mobility in polycrystalline titanium dioxide. Advanced Materials Interfaces, 1(5):1400078. https://doi.org/10.1002/admi.201400078

Wang, M. and Duan, B. (2018). Materials and their biomedical applications. Encyclopedia of Biomedical Engineering, 1:135-152. https://doi.org/10.1016/B978-0-12-801238-3.99860-X

Wang, Z., Zhong, J., Liang, H., and Wang, J. (2013). Luminescence properties of lutetium based red-emitting phosphor NaLu(WO4)2:Eu3+. Optical Materials Express, 3(3):418-425. https://doi.org/10.1364/OME.3.000418

Wu, Y. and Ren, G. (2013). Energy transfer and radiative recombination processes in (Gd, Lu)3Ga3Al2O12:Pr3+ scintillators. Optical Materials, 35(12):2146-2154. http://dx.doi.org/10.1016/j.optmat.2013.05.039

Yanagida, T. (2018). Inorganic scintillating materials and scintillation detectors. In: Proceedings of the Japan Academy, Series B, Detect. 94(2):75-97. https://doi.org/10.2183/pjab.94.007

Yanagida, T., Fujimoto, Y., Yokota, Y., Kamada, K., Yanagida, S., Yoshikawa, A., Yagi, H., and Yanagitani, T. (2011). Comparative study of transparent ceramic and single crystal Ce doped LuAG scintillators. Radiation Measurements, 46(12):1503-1505. https://doi:10.1016/j.radmeas.2011.03.039

Yanagida, T., Kamada, K., Fujimoto, Y., Yagi, H., and Yanagitani, T. (2013). Comparative study of ceramic and single crystal Ce:GAGG scintillator. Optical Materials, 35(12):2480-2485. https://doi.org/10.1016/j.optmat.2013. 07.002

Yanagida, T., Kato, T., Nakauchi, D., and Kawaguchi, N. (2023). Fundamental aspects, recent progress and future prospects of inorganic scintillators. Japanese Journal of Applied Physics, 62:010508. https://doi.org/10.35848/1347-4065/ac9026

Yu, L., Zhang, L., Xing, C., Yang, J., Huang, S., Bao, Q., Wang, D., and Zhang, T. (2024). Microregion characterization of grain boundary defects and electron capture of CsPbI2Br perovskite. Energy Technology, 12(2):2300907. https://doi.org/10.1002/ente.202300907

Downloads

Published

2025-07-17

How to Cite

Lertloypanyachai, P., Kantuptim, P., Kunikata, T., Hassadee, A., Chewpraditkul, W., Kato, T., Nakauchi, D., Kawaguchi, N., & Yanagida, T. (2025). PREPARATION OF Lu2.5Y0.5(Al5-xGax)O12:Ce TRANSLUCENT CERAMIC FOR X-RAY DETECTION APPLICATIONS USING SPARK PLASMA SINTERING (SPS): Preparation of Lu2.5Y0.5(Al5-xGax)O12:Ce Translucent Ceramic for X-ray Detection Applications using SPS. Suranaree Journal of Science and Technology, 32(2), 030316(1–7). https://doi.org/10.55766/sujst9837

Issue

Section

Research Article

Categories