ENHANCED THERMOELECTRIC PROPERTIES of n-Bi2Se3 AND p-Bi0.4Sb1.6Te3 SYNTHESIZED BY USING HOT-PRESS METHOD
DOI:
https://doi.org/10.55766/sujst9078Keywords:
Bi2Se3, Bi0.4Sb1.6Te3, HP method, TE properties, zTAbstract
We present the thermoelectric characteristics of bulk samples of the n-type Bi2Se3 and p-type Bi0.4Sb1.6Te3 that were produced by the vacuum melt technique and then vacuum hot-pressed at 723 and 523 K, respectively. The samples were investigated for their crystalline structure, lattice parameter, bulk density, relative density, and thermoelectric properties by XRD, density kit, ZEM-3, and LFA, respectively. In the same temperature range of 325 to 525 K, the thermoelectric characteristics of bulk n-type Bi2Se3 and p-type Bi0.4Sb1.6Te3 were higher than the literature data. The Bi2Se3 and Bi0.4Sb1.6Te3 bulk samples have maximum zT is 0.84 and 0.88 at 329 K, respectively, and are considered high-performance materials for use in thermoelectric devices.
References
Belec, B., Ferfolja, K., Goršak, T., Kostevšek, N., Gardonio, S., Fanetti, M., and Valant, M. (2019). Inherent surface properties of adsorbent-free ultrathin Bi2Se3 topological insulator platelets. Scientific Reports, 9:19057. https://doi.org/10.1038/s41598-019-55646-1
Bohra, A.K., Bhatt, R., Singh, A., Basu, R., Bhattacharya, S., Meshram, K.N., Ahmad, S., Debnath, A.K., Chauhan, A.K., Bhatt, P., Shah, K., Bhotkar, K., Sharma, S., Aswal, D.K., Muthe, K.P., and Gadkari, S.C. (2017). Tellurium-free thermoelectrics: Improved thermoelectric performance of n-type Bi2Se3 having multiscale hierarchical architecture. Energy Conversion and Management, 145:415-424. https://doi.org/10.1016/j.enconman.2017.04.083
Byun, S., Cha, J., Zhou, C., Lee, Y.K., Lee, H., Park, S.H. Lee, W.B., and Chung, I. (2019). Unusual n-type thermoelectric properties of Bi2Te3 doped with divalent alkali earth metals. Journal of Solid State Chemistry, 269:396-400. https://doi.org/10.1016/j.jssc.2018.10.012
Caillat, T., Carle, M., Pierrat, P., Scherrer, H., and Scherrer, S. (1992). Thermoelectric properties of (BixSb1−x)2Te3 single crystal solid solutions grown by the T.H.M. method. Journal of Physics and Chemistry of Solids, 53(8):1121-1129. https://doi.org/10.1016/0022-3697(92)90087-T
Cao, Y.Q., Zhao, X.B., Zhu, T.J., Zhang, X.B., and Tu, J.P. (2008). Syntheses and thermoelectric properties of Bi2Te3/Sb2Te3 bulk nanocomposites with laminated nanostructure. Applied Physics Letters, 92:143106. https://doi.org/10.1063/1.2900960
Fana, X., Yang, F., Ronga, Z., Caia, X., and Li, G. (2015). Characterization and thermoelectric properties of Bi0.4Sb1.6Te3 nanostructured bulk prepared by mechanical alloying and microwave activated hot pressing. Ceramics International, 41(5):6817-6823. https://doi.org/10.1016/j.ceramint.2015.01.130
Feutelais, Y., Lendre, B., Rodier, N., and Agafonov, V. (1993). A study of the phases in the bismuth - tellurium system. Materials Research Bulletin, 50(6):591-596. https://doi.org/10.1016/0025-5408(93)90055-I
Goldsmid, H.J. (2010). Introduction to Thermoelectricity. 1st ed. Springer Series in Materials Science, 242p. https://doi.org/10.1007/978-3-642-00716-3
Hu, L., Wu, H., Zhu, T., Fu, C., He, J., Ying, P., and Zhao, X. (2015). Tuning multiscale microstructures to enhance thermoelectric performance of n-type bismuth-telluride-based solid solutions. Advanced Energy Materials, 5(17):1500411. https://doi.org/10.1002/aenm.201500411
Kaibe, H., Tanaka, Y., Sakata, M., and Nishida, I. (1989). Anisotropic galvanomagnetic and thermoelectric properties of n-type Bi2Te3 single crystal with the composition of a useful thermoelectric cooling material. JJournal of Physics and Chemistry of Solids, 50(9):945-950. https://doi.org/10.1016/0022-3697(89)90045-0
Lee, K.H., Kim, Y., Kim, D.H., Park, C.H., Kim, H.S., and Kim, S.I. (2021). Studies on phase formation behavior and thermoelectric transport properties of Cu-doped Bi2Te3-Bi2Se3 system. Journal of Materials Research and Technology, 15:4781-4789. https://doi.org/10.1016/j.jmrt.2021.10.049
Lee, P.Y., Chen, T.C., Huang, J.Y., Hsieh, H.L., and Jang, J.S.C. (2014). Enhancement of the thermoelectric performance in nano-/micro-structured p-type Bi0.4Sb1.6Te3 fabricated by mechanical alloying and vacuum hot pressing. Journal of Alloys and Compounds, 615(Supplement 1):S476-S481 https://doi.org/10.1016/j.jallcom.2013.12.068
Liu, R., Tan, X., Ren, G., Liu, Y., Zhou, Z., Liu, C., Lin, Y., and Nan, C. (2017). Enhanced thermoelectric performance of Te-Doped Bi2Se3−xTex bulks by self-propagating high-temperature synthesis. Crystals, 7(9):257 https://doi.org/10.3390/cryst7090257
Lu, X., Lu, P., Fan, Y., Zhou, W., Gu, S., Zhou, Z., Zhang, J., Su, L., Wang, L., and Jiang, W. (2019). Structurally nanocrystalline electrically monocrystalline Sb2Te3 with high thermoelectric performance. Scripta Materialia, 166:81-86. https://doi.org/10.1016/j.scriptamat.2019.03.013
Min, Y., Roh, J.W., Yang, H., Park, M., Kim, S.I., and Hwang, S. (2013). Surfactant-free scalable synthesis of Bi2Te3 and Bi2Se3 nanoflakes and enhanced thermoelectric properties of their nanocomposites. Advanced Materials, 25(1):1424-1424. https://doi.org/10.1002/adma.201370066
Palenskis, V. (2022). Free Electron Characteristic Peculiarities Caused by Lattice Vibrations in Metals. World Journal of Condensed Matter Physics, 12(2):9-17. https://doi.org/10.4236/wjcmp.2022.122002
Radingoana, P.M., Fritsch, S.G., Noudem, J., Olubambi, P.A., Chevallier, G., and Estournès, C. (2023). Microstructure and thermoelectric properties of Al-doped ZnO ceramic prepared by spark plasma sintering. Journal of the European Ceramic Society, 43(3):1009-1016. https://doi.org/10.1016/j.jeurceramsoc.2022.10.034
Sobota, J.A., Yang, S.L., Leuenberger, D., Kemper, A.F., Analytis, J.G., Fisher, I.R., Kirchmann, P.S., Devereaux, T.P. and Shen, Z.X. (2014). Ultrafast electron dynamics in the topological insulator Bi2Se3 studied by time-resolved photoemission spectroscopy. Journal of Electron Spectroscopy and Related Phenomena, 195:249-257. https://doi.org/10.1016/j.elspec.2014.01.005
Suh, D., Lee, S., Mun, H., Park, S.H., Lee, K.H., Kim, S.W., Choi, J.Y., and Baik, S. (2015). Enhanced thermoelectric performance of Bi0.5Sb1.5Te3-expanded graphene composites by simultaneous modulation of electronic and thermal carrier transport. Nano Energy, 13:67-76. https://doi.org/10.1016/j.nanoen.2015.02.001
Sun, G., Li, L., Qin, X., Li, D., Zou, T., and Xin, H. (2015). Enhanced thermoelectric performance of nanostructured topological insulator Bi2Se3. Applied Physics Letters, 106(5):053102 https://doi.org/10.1063/1.4907252
Yan, X., Poudel, B., Ma, Y., Liu, W., Joshi, G., Wang, H., Lan, Y., Wang, D., Chen, G., and Ren, Z. (2010). Experimental studies on anisotropic thermoelectric properties and structures of n-type Bi2Te2.7Se0.3. Nano Letters, 10(9):3373-3378. https://doi.org/10.1021/nl101156v
Yim, W.M. and Rosi, F.D. (1972). Compound tellurides and their alloys for Peltier cooling-A review. Solid-State Electronics, 15(10):1121-1140. https://doi.org/10.1016/0038-1101(72)90172-4
Zhang, G., Kirk, B., Jauregui, L.A., Yang, H., Xu, X., and Chen, Y.P. (2011). Rational synthesis of ultrathin n-type Bi2Te3 nanowires with enhanced thermoelectric properties, Nano Letters, 12(1):56-60. https://doi.org/10.1021/nl202935k
Zhang, T., Jiang, J., Xiao, Y., Zhai, Y., Yang, S., and Xu, G. (2013). In situ precipitation of te nanoparticles in p-type bisbte and the effect on thermoelectric performance. ACS Applied Materials & Interfaces, 5(8):3071-3074. https://doi.org/10.1021/am303145v
Zhang, Y., Ma, H., Sun, B., Liu, B., Liu, H., Kong, L., Liu, B., Jia, X., and Chen, X. (2017). Thermoelectric performance of graphene composited BiSbTe bulks by high pressure synthesis. Journal of Alloys and Compounds, 715:344-348. https://doi.org/10.1016/j.jallcom.2017.05.004
Zhang, Z., Tao, Q., Bai, H., Tang, H., Cao, Y., Shi, Y., Wu, J., Su, X., and Tang, X. (2022). Regulation of exciton for high thermoelectric performance in (Bi,Sb)2Te3 alloys via doping with Pb and multi-scale microstructure. Journal of the European Ceramic Society, 41(15):7703-7710. https://doi.org/10.1016/j.jeurceramsoc.2021.08.041








