NOVEL PHOTOSENSITIZER FROM RED LOTUS FLOWER EXTRACT FOR NATURAL DYE-SENSITIZED SOLAR CELLS

Authors

  • Narid Prachumrak Natural materials research group, Division of Chemistry, Faculty of Science, Udon Thani Rajabhat University, 64 Taharn Road, Muang, Udon Thani 41000, Thailand,
  • Natthamon Prajudtasri Dr. Natthamon Prajudtasri, Natural materials research group, Division of Chemistry, Faculty of Science, Udon Thani Rajabhat University, 64 Taharn Road, Muang, Udon Thani 41000, Thailand,
  • Wipaporn Kitisriworaphan Dr. Wipaporn Kitisriworaphan, Natural materials research group, Division of Chemistry, Faculty of Science, Udon Thani Rajabhat University, 64 Taharn Road, Muang, Udon Thani 41000, Thailand,

DOI:

https://doi.org/10.55766/sujst-2023-02-e087

Keywords:

Natural Dye-Sensitized Solar Cells, Nymphaea pubescens Willd, Red Lotus, Photosensitizer

Abstract

Natural dye-sensitized solar cells (NDSSCs) convert solar radiation into electrical energy using sensitization of dyes which is obtained from a natural source. In this study, a novel photosensitizer was extracted from the petal of Red Lotus flowers (Nymphaea pubescens Willd.) using methanol as a solvent. Various NDSSCs using an extracted dye as a photosensitizer were fabricated and the efficiency of cells was investigated. The petal dye showed a high absorption band in the visible region at 540 nm indicating a good light absorption performance. The PCE of NDSSCs based on the petal dye in methanol was 0.208 - 0.281%. The filling factor (FF), photocurrent density (𝐽SC), and photovoltage (𝑉OC) of NDSSCs were in the range of 0.621 - 0.668, 0.615 - 0.855 mA/cm2, and 0.506 - 0.523 V, respectively.

References

Ahliha A. H, Nurosyid F., Supriyanto A., and Kusumaningsih T. (2018). Optical properties of anthocyanin dyes on TiO2 as photosensitizers for application of dye-sensitized solar cell (DSSC). IOP Conference Series: Materials Science and Engineering; Sep 4-5, 2017; Surakarta, Indonesia, p. 1-5.

Arguelles E. D. L.R. (2019). Species composition of algal epiphyton of Pink Lotus (Nymphaea pubescens Willd) found in Laguna de Bay (Philippines). Walailak J Sci & Tech, 17(3): 237-256.

Barreto J. C. G., Tita D. L., and Orlandi M. O. (2019). Development of an automated method to perform a quantitative study of particle size distribution and the effect of a conductive layer in scanning electron microscopy. Quim. Nova, 42(4): 447-452.

Chougala L. S., Yatnatti M. S., Linganagoudar R. K., Kamble R. R., and Kadadevarmath J. S. (2017). A simple approach on synthesis of TiO2 nanoparticles and its application in dye sensitized solar cells. J. Nano-Electron. Phys., 9(4): 04005-1-04005-6.

Do Q. D., Angkawijaya A. E., Tran-Nguyen P. L., Huynh L. H., Soetaredjo F. E., Ismadji S., and Ju Y. H. (2014). Effect of extraction solvent on total phenol content, total flavonoid content, and antioxidant activity of Limnophila aromatic. J Food Drug Anal, 22: 296-302.

Genta D., Jara J., and Villanueva R. (2017). Dye-sensitized solar cells using aloe vera and cladode of cactus extracts as natural sensitizers. Chem. Phys. Lett., 679: 97-101.

Ghrairi N., and Bouaicha M. (2012). Structural, morphological, and optical properties of TiO2 thin films synthesized by the electro phoretic deposition technique. Nanoscale Res. Lett., 7: 1-7.

Hamadanian M., Safaei-Ghomi J., Hosseinpour M., Masoomi R., and Jabbari V. (2014). Uses of new natural dye photosensitizers in fabrication of high potential dye-sensitized solar cells (DSSCs). Mater Sci Semicond Process, 27: 733-739.

Hernández-Martínez A.R., Estevez M., Vargas S., Quintanilla F., and Rodríguez R. (2012). Natural pigment-based dye-sensitized solar cells. J. Appl. Res. Technol., 10(1): 38-47.

Heneczkowski M., Kopacz M., Nowak D., and Kuźniar A. (2001). Infrared spectrum analysis of some flavonoids. Acta Pol Pharm, 58(6): 415-420.

Hug H., Bader M., Mair P., and Glatzel T. (2014). Biophotovoltaics: natural pigments in dye-sensitized solar cells. Appl. Energy, 115: 216-225.

Jeng M. J., Wung Y. L., Chang L. B., and Chow L. (2013). Particle size effects of TiO2 layers on the solar efficiency of dye-sensitized solar cells. Int. J. Photoenergy, 1-9.

Kawakami R., Yuasa T., Sato Y., Mori Y., Adachi M., and Yoshikado S. (2013). Effects of particle size on properties of TiO2 nanoparticle thin films deposited by electrophoresis. Key Eng. Mater., 566: 199-203.

Nazeeruddin M.K., Humphry-Baker R., Liska P., and Grätzel M. (2003). Investigation of sensitizer adsorption and the influence of protons on current and voltage of a dye-sensitized nanocrystalline TiO2 solar cell. J. Phys. Chem., 107: 8981-8987.

O’Regan B., and Grätzel M. (1991). A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films. Nature., 353: 737-740.

Phaechamud T., and Chitrattha S. (2016). Pore formation mechanism of porous poly(DL-lactic acid) matrix Membrane. Mater. Sci. Eng. C, 61: 744-752.

Prachumrak N., Sudyoadsuk T., Thangthong A., Nalaoh P., Jungsuttiwong S., Daengngern R., Namuangruk S., Pattanasattayavonga P., and Promarak V. (2017). Improvement of D–π–a organic dye-based dye-sensitized solar cell performance by simple triphenylamine donor substitutions on the π-linker of the dye. Mater. Chem. Front., 1(6): 1059-1072.

Prajudtasri N., and Kitisriworaphan W. (2014). Preliminary phytochemicals screening and antioxidant activity of crude extracts from Nymphaea lotus L. var. pubescens Hook.F.&Thomson. Pure and Applied Chemistry International Conference 2014 (PACCON2014); Jan 8-10, 2014; Khon Kaen, Thailand, p. 364-367.

Selvakumari E., Shantha A., Sreenath Kumar C., and Purushoth Prabhu T. (2016). Phytochemistry and pharmacology of the genus Nymphaea. J. Acad. Ind. Res., 5(7): 98-108.

Sharma K., Sharma V., and Sharma S. S. (2018). Dye-sensitized solar cells: Fundamentals and current status. Nanoscale Res. Lett., 13(381): 1-46.

Sisa M., Bonnet S. L., Ferreira D., and Van der Westhuizen J. H. (2010). Photochemistry of flavonoids. Molecules, 15(8): 5196-245.

Sowemimo A. A., Omobuwajo O. R, and Adesanya S. A. (2007). Constituents of Nymphaea lotus Linn. Nig. J. Nat. Prod. and Med., 11: 1-2.

Syafinar R., Gomesh N., Irwanto M., Fareq M., and Irwan Y.M. (2015). Chlorophyll pigments as nature based dye for dye-sensitized solar cell (DSSC). Energy Procedia, 79: 896-902.

Zhu M., Zheng X., Shu Q., Li H., Zhong P., Zhang H., Xu Y., Wang L., and Wang L. (2012). Relationship between the composition of flavonoids and flower colors variation in tropical Water Lily (Nymphaea) cultivars. PLoS one, 7(4): 1-11.

Downloads

Published

2023-08-07

How to Cite

Prachumrak, N., Prajudtasri, N., & Kitisriworaphan, W. (2023). NOVEL PHOTOSENSITIZER FROM RED LOTUS FLOWER EXTRACT FOR NATURAL DYE-SENSITIZED SOLAR CELLS. Suranaree Journal of Science and Technology, 30(2), 030102(1–8). https://doi.org/10.55766/sujst-2023-02-e087

Issue

Section

Research Article

Categories