DIELECTRIC AND THERMOELECTRIC PROPERTIES OF 30LI2O: 3MOO3: 40BI2O3: 20TEO2: 7CUO GLASS-CERAMIC MATERIAL

Authors

  • NARONG SANGWARANATEE -
  • Peerapong Yamchumporn Center of Excellence in Glass Technology and Materials Science, Nakhon Pathom Rajabhat University, Meuang, Nakhon Pathom 73000, Thailand
  • Kitipun Boonin Center of Excellence in Glass Technology and Materials Science, Nakhon Pathom Rajabhat University, Meuang, Nakhon Pathom 73000, Thailand.
  • Narit Triamnak Department of Materials Science and Engineering, Faculty of Engineering and Industrial Technology, Silpakorn University, Nakhon Pathom, 73000, Thailand.
  • Kunchit Singsoog Thermoelectric Research Laboratory, Center of Excellence on Alternative Energy, Research and Development Institution, Sakon Nakhon Rajabhat University, Sakon Nakhon, 47000 Thailand.
  • Tosawat Seetawan Thermoelectric Research Laboratory, Center of Excellence on Alternative Energy, Research and Development Institution, Sakon Nakhon Rajabhat University, Sakon Nakhon, 47000 Thailand.
  • Pichet Limsuwan Department of Physics, Faculty of Science, King Mongkut's Institute of Technology Ladkrabang Bangkok, Thailand.

DOI:

https://doi.org/10.55766/sujst5267

Keywords:

Melt-quenching, Dielectric constant, Seebeck coefficient, Power factor

Abstract

In this study, the physical and thermoelectric characteristics of glass-ceramic materials are examined to provide the thermoelectric performance of 30Li2O: 3MoO3: 40Bi2O3: 20TeO2: 7CuO samples that were synthesized utilizing the melt-quenching process. Archimedes' Principle was used to determine the physical properties of the sample, showing a density of 4.53 g/cm3. An X-ray diffractometer (XRD) used to analyze the crystal structure revealed the Bismuth Oxide phase. The results of measuring with the LCR Meter for the frequency range were set from 50 Hz to 1 MHz at room temperature, showing the dielectric constant (ε’) and the dielectric loss (ε”) that tended to decrease with increasing frequency. Thermoelectric properties were examined in a temperature range of 300 K to 600 K indicating the electrical resistivity, the Seebeck coefficient, and the power factor. By calculating the efficiency of thermoelectric materials, the power factor term is considered at which temperature it shows its highest value. In this work, it was shown on 6.99 mW/mK2 at a temperature of 474 K

References

Bale, S. and Rahman, S. (2012). Electrical conductivity studies of Bi2O3-Li2O-ZnO-B2O3 glasses. Materials Research Bulletin, 47(5):1153-1157. https://doi.org/10.1016/j.materresbull.2012.02.007

Chowdari, B., Tan, K., and Ling, F. (1998). Synthesis and characterization of xCu2O: yTeO2: (1-x-y)MoO3 glass system. Solid State Ionics. 113-115:711-721. https://doi.org/10.1016/S01672738(98)00334-8

Dimitrov, V. and Komatsu, T. (2013). Optical basicity and chemical bonding of Bi2O3 containing glasses. Journal of Non-Crystalline Solids, 382:18-23. https://doi.org/10.1016/j.jnoncrysol.2013.10.005

El-Mallawany, R. (1995). Devitrification and vitrification of tellurite glasses. Journal of Materials Science: Materials in Electronics, 6(1):1-3. https://doi.org/10.1007/BF00208125

El-Mallawany, R.A.H. and El-Mallawany, R.A.H. (2001). Tellurite Glasses Handbook: Physical Properties and Data 1st ed. CRC Press, 78p. https://doi.org/10.1201/9781420042085

Gonon, M. and Dupla, F. (2021). Glass-ceramics and their applications. Encyclopedia of Materials: Technical Ceramics and Glasses, 2:709-727. https://doi.org/10.1016/B978-0-12-818542-1.00008-4

Liu, H., Shi, X., Xu, F., Zhang, L., Zhang, W., Chen, L., Li, Q., Uher, C., Day, T., and Snyder, J.G. (2012). Copper ion liquid-like thermoelectrics. Nature Materials, 11:422-425. https://doi.org/10.1038/NMAT3273

Marshall, J.M. and Owen, A.E. (1971). Drift mobility studies in vitreous arsenic triselenide. The Philosophical Magazine: A Journal of Theoretical Experimental and Applied Physics, 24(192):1281-1305. https://doi.org/10.1080/14786437108217413

Ohtaki, M., Tsubota, T., Eguchi, K., and Arai, H. (1996). High-temperature thermoelectric properties of (Zn1-xAlx)O. Journal of Applied Physics, 79(3):1816-1818. https://doi.org/10.1063/1.360976

Ohta, S., Nomura, T., Ohta, H., and Koumoto, K. (2005). High-temperature carrier transport and thermoelectric properties of heavily La- Or Nb-doped SrTiO3 single crystals. Journal of Applied Physics, 97(3):034106. https://doi.org/10.1063/1.1847723

Petersen, K., Birkholz, U., and Adler, D. (1973). Properties of Crystalline and Amorphous Silicon Telluride. Physical Review B, 8(4):1453-1461. https://doi.org/10.1103/PhysRevB.8.1453

Sammes, N.M., Tompsett, G.A., Näfe, H., and Aldinger, F. (1999). Bismuth based oxide electrolytes- structure and ionic conductivity. Journal of the European Ceramic Society, 19(10):1801-1826. https://doi.org/10.1016/S0955-2219(99)00009-6

Shikano, M. and Funahashi, R. (2003). Electrical and thermal properties of single-crystalline (Ca2CoO3)0.7CoO2 with a Ca3Co4O9 structure. Applied Physics Letters, 82(12):1851-1853. 1851-1853. https://doi.org/10.1063/1.1562337

Souri, D. and Shahmoradi, Y. (2017) Calorimetric analysis of non-crystalline TeO2-V2O5-Sb2O3. Journal of Thermal Analysis and Calorimetry, 129(1):601-607. https://doi.org/10.1007/s10973-017-6151-5

Souri, D. (2017). Physical and thermal characterization and glass stability criteria of amorphous silver-vanadate-tellurate system at different heating rates: Inducing critical Ag2O/V2O5 ratio. Journal of Non-Crystalline Solids, 475:136-143. https://doi.org/10.1016/j.jnoncrysol.2017.09.008

Terasaki, I., Sasago, Y., and Uchinokura, K. (1997). Large thermoelectric power in NaCo2O4 single crystals. Physical Review B - Condensed Matter and Materials Physics, 56(20):R12685-R12687. https://doi.org/10.1103/PhysRevB. 56.R12685

Varshneya, A. and Mauro, J. (2019). Electronic conduction. Fundamentals of Inorganic Glasses Third Edition. Publishing Elsevier, p. 443-472. https://doi.org/10.1016/B978-0-12-816225-5.00016-X

Zhao, G., Tian, Y., Fan, H., Zhang, J., and Hu, L. (2013). Properties and structures of Bi2O3-B2O3-TeO2 glass. Journal of Materials Science and Technology, 29(3):209-214. https://doi.org/10.1016/j.jmst.2012.11.003

Downloads

Published

2025-04-17

How to Cite

SANGWARANATEE, N., Yamchumporn, P., Boonin, K., Triamnak, N., Singsoog, K., Seetawan, T., & Limsuwan, P. (2025). DIELECTRIC AND THERMOELECTRIC PROPERTIES OF 30LI2O: 3MOO3: 40BI2O3: 20TEO2: 7CUO GLASS-CERAMIC MATERIAL. Suranaree Journal of Science and Technology, 32(1), 030275(1–5). https://doi.org/10.55766/sujst5267

Issue

Section

Research Article

Categories