TIO2-MOS2 PAPER BASED MEMBRANE FOR SOLAR EVAPORATION
DOI:
https://doi.org/10.55766/sujst-2024-02-e04940Keywords:
Desalination, MoS2-TiO2, photothermal, solar evaporator, solar illuminationAbstract
Clean water scarcity is a critical issue faced by the world. It was caused by insufficient potable water supply and a high cost of water purification systems. As a result, a photothermal evaporator system with the property to absorb light/solar energy and then convert it to heat energy has been rapidly developed. In this work, a solar-driven water evaporation was designed for desalination. The solar evaporator comprises a photothermal molybdenum disulfide-titanium dioxide (MoS2-TiO2) composite layer supported onto a cheap filter paper attached. The filter paper was attached to polystyrene foam for support and cotton thread in the centre of the filter paper for water transportation. MoS2-TiO2 composite was synthesized and coated onto the filter paper using a simple vacuum-assisted method. Before the solar-driven water evaporation testing, the MoS2-TiO2 composite was first characterized using XRD and Raman spectroscopy. The characterization results indicate that MoS2 introduction into the TiO2 structure improved the photosensitivity due to the reduction of the bandgap energy from 3.1 eV for TiO2 to 1.6 eV. The performance of the developed solar evaporator was tested using 35,000 ppm NaCl solution under sunlight for 24 h intermittently. The TiO2-MoS2 solar evaporator was observed to have the highest photothermal ability, with 0.807 kg‧m-2‧h-1 evaporation performance and 55.9 % photothermal efficiency compared to other solar evaporators. This indicated that introducing the photothermal MoS2-TiO2 layer could enhance the solar evaporator performances, making it promising for the desalination application, particularly in impoverished areas with water scarcity.
References
Ai, S., Wang, Y.-N., Li, T.-J., Chen, Y.-Z., He, C.-Y., Liu, B.-H., Liu, G., and Gao, X.-H. (2022). Commercial black dye without plasmonic effect: A low-cost viable candidate as a solar absorber for photo-thermal interfacial evaporation and desalination? Journal of Cleaner Production, 380(Part 1):134788. https://doi.org/10.1016/j.jclepro.2022.134788
Ai, S., Wang, Y.-N., Li, T.-J., Chen, Y.-Z., He, C.-Y., Liu, B.-H., Liu, G., and Gao, X.-H. (2023). A dye-based desalinating evaporator independent on solar absorber of excellent optical properties for efficient desalination. Desalination, 564:116811. https://doi.org/10.1016/j.desal.2023.116811
Carneiro, J.O., Vasconcelos, G., Azevedo, S., Jesus, C., Palha, C., Gomes, N., and Teixeira, V. (2014). The evaluation of the thermal behaviour of a mortar based brick masonry wall coated with TiO2 nanoparticles: An experimental assessment towards energy efficient buildings. Energy and Buildings, 81:1-8. https://doi.org/10.1016/j.enbuild.2014.06.006
Chen, Q., Pei, Z., Xu, Y., Li, Z., Yang, Y., Wei, Y., and Ji, Y. (2018). A durable monolithic polymer foam for efficient solar steam generation. Chemical Science, 9(3):623-628. https://doi.org/10.1039/C7SC02967E
Cheng, L., Zuo, L., Yan, S., Shen, J., Li, C., Che, Y., Wang, L., Anton, R., and Bian, T. (2023). In situ growth of polydopamine modified ZIF-L arrays on air-laid paper as flexible evaporator for efficient solar desalination. Desalination, 565:116832. https://doi.org/10.1016/j.desal.2023.116832
Cheng, X., Kong, Y., Gao, Y., Dan, H., Wei, Y., Yin, W., Gao, B., and Yue, Q. (2022a). One-step construction of P(AM-DMDAAC)/GO aerogel evaporator with Janus wettability for stable solar-driven desalination. Separation and Purification Technology, 303:122285. https://doi.org/10.1016/j.seppur.2022.122285
Cheng, X., Wang, L., Sun, C., Zhao, W., Liu, X., Zhuang, Z., Liu, S., and Zhao, Q. (2022b). Defect-driven selective oxidation of MoS2 nanosheets with photothermal effect for photo-catalytic hydrogen evolution reaction. Chemical Engineering Journal, 439:135757. https://doi.org/10.1016/j.cej.2022.135757
Chien, H.-W., Tsai, M.-Y., Kuo, C.-J., and Lin, C.-L. (2021). Well-dispersed silver nanoparticles on cellulose filter paper for bacterial removal. Nanomaterials (Basel, Switzerland), 11(3):595. https://doi.org/10.3390/nano11030595
Feng, B., Liu, C., Yan, W., Geng, J., and Wang, G. (2019). MoS2 nanotubes loaded with TiO2 nanoparticles for enhanced electrocatalytic hydrogen evolution. RSC Advances, 9:26487-26494. https://doi.org/10.1039/C9RA05041H
Fuzil, N.S., Othman, N.H., Alias, N.H., Marpani, F., Mat Shayuti, M.S., Shahruddin, M.Z., Mohd Razlan, M.R., Abd Rahman, N., Lau, W.J., Othman, M.H.D., Ismail, A.F., Kusworo, T.D., and Ul-Hamid, A. (2023). MoS2- TiO2 coated PVDF-based hollow fiber membranes for permeate flux enhancement in membrane distillation. Journal of Environmental Chemical Engineering, 11(3):109866. https://doi.org/10.1016/j.jece.2023.109866
Guo, C., Zhang, W., Liu, K., Zhang, T., Liu, Q., Cao, H., and Li, L. (2023). Developing an expandable ferric tannate/gallate polyurethane sponge evaporator for efficient solar desalination. Applied Thermal Engineering, 221:119837. https://doi.org/10.1016/j.applthermaleng.2022.119837
Guo, C.-L., Miao, E.-D., Zhao, J.-X., Liang, L., and Liu, Q. (2019). Paper-based integrated evaporation device for efficient solar steam generation through localized heating. Solar Energy, 188:1283-1291. https://doi.org/10.1016/j.solener.2019.07.023
Guo, Q., An, Q., Yi, H., Jia, F., and Song, S. (2022a). Double-layered montmorillonite/MoS2 aerogel with vertical channel for efficient and stable solar interfacial desalination. Applied Clay Science, 217:106389. https://doi.org/10.1016/j.clay.2021.106389
Guo, Q., Yi, H., Jia, F., and Song, S. (2022b). Design of MoS2/MMT bi-layered aerogels integrated with phase change materials for sustained and efficient solar desalination. Desalination, 541:116028. https://doi.org/10.1016/j.desal.2022.116028
Hasan, H., Alsadaie, S., Al-Obaidi, M. A., and Mujtaba, I.M. (2023). Dynamic modelling and simulation of industrial scale multistage flash desalination process. Desalination, 553:116453. https://doi.org/10.1016/j.desal.2023.116453
He, Z., Wu, H., Shi, Z., Gao, X., Sun, Y., and Liu, X. (2022). Mussel-inspired durable TiO2/PDA-Based superhydrophobic paper with excellent self-cleaning, high chemical stability, and efficient oil/water separation properties. Langmuir, 38(19):6086-6098. https://doi.org/10.1021/acs.langmuir.2c00429
Hezam, A., Alkanad, K., Bajiri, M.A., Strunk, J., Takahashi, K., Drmosh, Q.A., Al-Zaqri, N., and Krishnappagowda, L.N. (2023). 2D/1D MoS2/TiO2 heterostructure photocatalyst with a switchable CO2 Reduction Product. Small Methods, 7(1):2201103. https://doi.org/10.1002/smtd.202201103
Jarosz, G., Marczyński, R., and Signerski, R. (2020). Effect of band gap on power conversion efficiency of single-junction semiconductor photovoltaic cells under white light phosphor-based LED illumination. Materials Science in Semiconductor Processing, 107:104812. https://doi.org/10.1016/j.mssp.2019.104812
Jiang, J., Jiang, H., Xu, Y., and Ai, L. (2022). 1T/2H MoS2 nanoflowers embedded in porous PDMS sponge with high salt-resistance for efficient and durable solar desalination. Desalination, 539:115943. https://doi.org/10.1016/j.desal.2022.115943
Khoshrou, I., Jafari Nasr, M.R., and Bakhtari, K. (2017). New opportunities in mass and energy consumption of the Multi-Stage Flash Distillation type of brackish water desalination process. Solar Energy, 153:115-125. https://doi.org/10.1016/j.solener.2017.05.021
Kim, Y.E., Lim, J., Lee, H., Lee, E., Kim, D.Y., Jun, Y.-S., Han, J.H., and Lee, S.H. (2022). Solar-driven enhanced chemical adsorption and interfacial evaporation using porous graphene-based spherical composites. Chemosphere, 291(Part 3):133013. https://doi.org/10.1016/j.chemosphere.2021.133013
Kospa, D.A., Ahmed, A.I., Samra, S.E., El-Hakam, S.A., and Ibrahim, A.A. (2022). Flexible CuO-rGO/ PANI thermal absorber with high broadband photoresponse and salt resistance for efficient desalination of oil-contaminated seawater. Desalination, 528:115612. https://doi.org/10.1016/j.desal.2022.115612
Li, J., Shao, Y., Song, W., Li, X., Li, Y., Yang, L., Xie, X., and Yan, L. (2023). Ultrahigh solar vapor evaporation rate of super-hydrophilic aerogel by introducing environmental energy and convective flow. Chemical Engineering Journal, 466:143281. https://doi.org/10.1016/j.cej.2023.143281
Li, P., Gao, M., Sun, L., Xu, H., Dong, X., and Lin, J. (2022). Preparation of heterostructured TiO2/MoS2 for efficient photocatalytic rhodamine B degradation. Materials Advances, 3(4):2185-2190. https://doi.org/10.1039/D1MA01050F
Lin, Y.-X., Liou, Y.-K., Lee, S.L., Chen, S.-Y., Tao, F.-T., Cheng, T.-W., and Tung, K.-L. (2023). Preparation of PVDF/PMMA composite membrane with green solvent for seawater desalination by gap membrane distillation. Journal of Membrane Science, 679:121676. https://doi.org/10.1016/j.memsci.2023.121676
Mehta, M., Singh, A.P., Kumar, S., Krishnamurthy, S., Wickman, B., and Basu, S. (2018). Synthesis of MoS2- TiO2 nanocomposite for enhanced photocatalytic and photoelectrochemical performance under visible light irradiation. Vacuum, 155:675-681. https://doi.org/10.1016/j.vacuum.2018.05.052
Mi, J., Wu, X., Capper, J., Li, X., Shalaby, A., Wang, R., Lin, S., Hajj, M., and Zuo, L. (2023). Experimental investigation of a reverse osmosis desalination system directly powered by wave energy. Applied Energy, 343:121194. https://doi.org/10.1016/j.apenergy.2023.121194
Mitra, D., Chanda, K., Bhattacharjee, S., Bairi, P., Chattopadhyay, K.K., and Chattopadhyay, P. (2023). Enhanced interfacial evaporation and desalination by solar heat localisation using nitrogenated graphitic carbon and Co3O4 nanorods. Solar Energy Materials and Solar Cells, 257:112361. https://doi.org/10.1016/j.solmat.2023.112361
Mulu, M., RamaDevi, D., Belachew, N., and Basavaiah, K. (2021). Hydrothermal green synthesis of MoS2 nanosheets for pollution abatement and antifungal applications. RSC Advances, 11(40):24536-24542. https://doi.org/10.1039/D1RA03815J
Ramakrishnan, M. and Raina, G. (2022). Hydrothermally synthesized 2H-MoS2 under optimized conditions - A structure and morphology analysis. Physica Scripta, 97(12):125808. https://doi.org/10.1088/1402-4896/ac9d6f
Ridwan, M.G., Altmann, T., Yousry, A., and Das, R. (2023). Intelligent framework for coagulant dosing optimization in an industrial-scale seawater reverse osmosis desalination plant. Machine Learning with Applications, 12:100475. https://doi.org/10.1016/j.mlwa.2023.100475
Saleque, A.M., Ma, S., Ahmed, S., Hossain, M.I., Qarony, W., and Tsang, Y.H. (2021). Solar driven interfacial steam generation derived from biodegradable luffa sponge. Advanced Sustainable Systems, 5(5):2000291. https://doi.org/10.1002/adsu.202000291
Sang, H., Tang, C., Ma, K., and Li, X. (2023). Sustainable production of clean water: 1 T-MoS2/PDA composite enhanced the photothermal conversion. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 674:131838. https://doi.org/10.1016/j.colsurfa.2023.131838
Sheng, C., Yang, N., Yan, Y., Shen, X., Jin, C., Wang, Z., and Sun, Q. (2020). Bamboo decorated with plasmonic nanoparticles for efficient solar steam generation. Applied Thermal Engineering, 167:114712. https://doi.org/10.1016/j.applthermaleng.2019.114712
Sun, M., Yang, H., Wang, X., Gao, X., Wang, C., and Ho, S.-H. (2023). Wood-inspired anisotropic PU/chitosan/MXene aerogel used as an enhanced solar evaporator with superior salt-resistance. Desalination, 555:116462. https://doi.org/10.1016/j.desal.2023.116462
Tan, C., Rudd, C.D., Parsons, A.J., Sharmin, N., and Ahmed, I. (2022). L-DOPA coating improved phosphate glass fibre strength and fibre/matrix interface. Journal of the Mechanical Behavior of Biomedical Materials, 136:105480. https://doi.org/10.1016/j.jmbbm.2022.105480
Trinh, B., Cho, H., Lee, D., Omelianovych, O., Kim, T., Nguyen, S., Choi, H.-S., Kim, H., and Yoon, I. (2023).
Dual-functional solar-to-steam generation and SERS detection substrate based on plasmonic nanostructure. Nanomaterials, 13(6):1003. https://doi.org/10.3390/nano13061003
Wang, Q., Qin, Y., Jia, F., Li, Y., and Song, S. (2021). Magnetic MoS2 nanosheets as recyclable solar-absorbers for high-performance solar steam generation. Renewable Energy, 163:146-153. https://doi.org/10.1016/j.renene.2020.07.019
Wang, Q., Qiu, L., Jia, Y., Chang, Y., Tan, X., Yang, L., and Chen, H. (2019). Design of carbon loaded porous TiO2 foams by the hydrothermal-assisted annealing carbonization of fruit residue for solar-driven water evaporation. Solar Energy Materials and Solar Cells, 202:110116. https://doi.org/10.1016/j.solmat.2019.110116
Wen, J., Li, X., Zhang, H., Zheng, S., Yi, C., Yang, L., and Shi, J. (2023). Architecting Janus hydrogel evaporator with polydopamine-TiO2 photocatalyst for high-efficient solar desalination and purification. Separation and Purification Technology, 304:122403. https://doi.org/10.1016/j.seppur.2022.122403
Wu, D., Dai, Z., Wang, C., Gao, Y., Chen, B., and Zhang, X. (2023). Scalable and high-efficiency lignocellulose sponge-based evaporators for solar-driven desalination and desiccant regeneration. Separation and Purification Technology, 318:124032. https://doi.org/10.1016/j.seppur.2023.124032
Xiao, J., Guo, Y., Luo, W., Wang, D., Zhong, S., Yue, Y., Han, C., Lv, R., Feng, J., Wang, J., Huang, W., Tian, X., Xiao, W., and Shen, Y. (2021). A scalable, cost-effective and salt-rejecting MoS2/SA@melamine foam for continuous solar steam generation. Nano Energy, 87:106213. https://doi.org/10.1016/j.nanoen.2021.106213
Xu, R., Cui, H., Sun, K., Song, X., Yang, K., Wei, N., Hou, C., and Zhao, M. (2022). Controllable 3D interconnected featured pore structure of transition metal borides-carbonitride/MoS2 for efficiently solar evaporation and wastewater purification. Chemical Engineering Journal, 446(Part 4):137275. https://doi.org/10.1016/j.cej.2022.137275
Xu, R., Wei, N., Li, Z., Song, X., Li, Q., Sun, K., Yang, E., Gong, L., Sui, Y., Tian, J., Wang, X., Zhao, M., and Cui, H. (2021). Construction of hierarchical 2D/2D Ti3C2/MoS2 nanocomposites for high-efficiency solar steam generation. Journal of Colloid and Interface Science, 584:125-133. https://doi.org/10.1016/j.jcis.2020.09.052
Yan, J., Yin, L., Lv, H., Qiu, R., Yang, X., Cheng, J., Han, T., Lu, H., Bui, H.V., Agathopoulos, S., Zhao, Y., Zhang, L., and Deng, L. (2023). Novel efficient solar spherical evaporators with adjustable pores to control water supply and evaporation. Journal of Alloys and Compounds, 960:170674. https://doi.org/10.1016/j.jallcom.2023.170674
Ye, M., Tao, N., Zhou, X., Wang, X., Jin, W., Zhang, T., and Liu, X. (2023). A super-hydrophilic honeycomb activated carbon evaporator for simultaneous salt rejection and VOCs removal during solar-driven seawater desalination. Separation and Purification Technology, 311:123201. https://doi.org/10.1016/j.seppur.2023.123201
Yi, S.-C., Jung, C.Y., and Kim, W.J. (2011). Synthesis of Pt/PEI-MWCNT composite materials on polyethyleneimine-functionalized MWNTs as supports. Materials Research Bulletin, 46(12):2433-2440. https://doi.org/10.1016/j.materresbull.2011.08.025
Yoo, C., Ko, T.-J., Hwang, J.-H., Mofid, S.A., Stoll, S., Osorto, B., Morillo, L., Han, S.S., Rodriguez, K.L., Lundin, J.G., Lee, W.H., and Jung, Y. (2022). 2D MoS2-polyurethane sponge for solar-to-thermal energy conversion in environmental applications: Crude oil recovery and seawater desalination. Journal of Water Process Engineering, 47:102665. https://doi.org/10.1016/j.jwpe.2022.102665
Yuan, B., Yang, L., Yang, H., Bai, L., Wang, W., Wei, D., Liang, Y., and Chen, H. (2022). Flexible vacancy-mediated MoS2-x nanosheet arrays for solar-driven interfacial water evaporation, photothermal-enhanced photodegradation, and thermoelectric generation. Energy Conversion and Management, 252:115070. https://doi.org/10.1016/j.enconman.2021.115070
Zhang, B., Chen, H., Huang, Y., Lau, W.-M., and Zhou, D. (2023). Solar-driven evaporation device based on
coal-derived nanomaterials for efficient and stable desalination. Chemical Engineering Journal, 468:143689. https://doi.org/10.1016/j.cej.2023.143689
Zhang, Y., Yin, X., Yu, B., Wang, X., Guo, Q., and Yang, J. (2019). Recyclable polydopamine-functionalized sponge for high-efficiency clean water generation with dual-purpose solar evaporation and contaminant adsorption. ACS Applied Materials and Interfaces, 11(35):32559-32568. https://doi.org/10.1021/acsami.9b10076
Zhao, D., Duan, H., Yu, S., Zhang, Y., He, J., Quan, X., Tao, P., Shang, W., Wu, J., Song, C., and Deng, T. (2015). Enhancing localized evaporation through separated light absorbing centers and scattering centers. Scientific Reports, 5(1):17276. https://doi.org/10.1038/srep17276
Zheng, P., Tang, J., Zhou, Z., Gong, L., Yang, H., Jia, X., Li, X., Liu, Y., and Tan, L. (2021). Ultrafast synthesis of defective black TiO2 via one-step nan3 deflagration for high-efficiency solar water evaporation. Surfaces and Interfaces, 22:100901. https://doi.org/10.1016/j.surfin.2020.100901
Zhong, C., Weng, W., Liang, X., Gu, D., and Xiao, W. (2020). One-step molten-salt synthesis of anatase/rutile bi-phase TiO2@MoS2 hierarchical photocatalysts for enhanced solar-driven hydrogen generation. Applied Surface Science, 507:145072. https://doi.org/10.1016/j.apsusc.2019.145072
Zhong, X., Wu, Y., Zhang, P., Chen, Y., Cai, Y., Wang, W., Min, X., Xiong, J., and Li, M. (2023). Turnover polypyrrole decorated cotton fabric based solar evaporator for cost-effective and steady desalination. Journal of Cleaner Production, 417:138088. https://doi.org/10.1016/j.jclepro.2023.138088
Zhu, S., Jia, X., Ni, Y., Pan, B., Long, Y., Miao, D., and Yan, X. (2023). A 3D solar-driven evaporator based on electrospun recycled PET film for efficient seawater desalination. Journal of Cleaner Production, 408, 137113. https://doi.org/10.1016/j.jclepro.2023.137113
Zhu, X., Uchikoshi, T., Suzuki, T.S., and Sakka, Y. (2007). Effect of polyethylenimine on hydrolysis and dispersion properties of aqueous Si3N4 Suspensions. Journal of the American Ceramic Society, 90(3):797-804. https://doi.org/10.1111/j.1551-2916.2007.01491.x








