FABRICATION AND STRUCTURAL STUDIES OF SPIN-COATED COBALT FERRITE LAYERS
DOI:
https://doi.org/10.55766/sujst-2024-03-e03565Keywords:
Spin coating, Cobalt ferrite, Memristor, Neuromorphic Computing, artificial intelligenceAbstract
Cobalt ferrite coating of various layers is fabricated on fluorine-doped tin oxide (FTO) substrate using a spin coater. A precursor sol of 0.1 M metal ion concentration is employed to develop layers of cobalt ferrite on FTO substrate. Various layers of cobalt ferrite are deposited on the FTO substrate at a rotation speed of 3000 revolutions per minute for 30 seconds. After deposition of each layer, the sample is kept for thermal baking at 200℃ for 5 min. Three samples of three different coats ranging from single layer to three layers are fabricated and thermally baked. These samples are then annealed at 500℃ for 7 hours in air ambient. Structural studies namely phase formation, chemical element analysis and surface morphology of the sample is carried out respectively using X-ray diffractometer (XRD), Energy-dispersive X-ray analysis (EDX) and Field Emission Scanning Electron Microscope (FESEM). These structural characterizations confirm the phase formation of cobalt ferrite. Spin-coated layers of cobalt ferrite can be widely employed in memristive applications due to its excellent resistive switching characteristics. The typical memristive applications are resistive random-access memory (RRAM), artificial intelligence (A.I.), neuromorphic computing, and hardware security. Such deposited cobalt ferrite layers also find applications in gas sensor fabrication, magneto-optic recording technology, and spintronics devices.
References
Adiba, A., Pandey, V., Ahmad, T., Nehla, P. and Munjal, S. (2023). Multilevel resistive switching with negative differential resistance in Al/NiO/ZnFe2O4/ITO ReRAM device. Physica B: Condensed Matter, 654:414742. https://doi.org/10.1016/j.physb.2023.414742
Angadi, V.J., Kozakov, A.T., Nicolski, A.V., Rusalev, Y.V., Ahmed, I.A., Kubrin, S.P. and Wang, S. (2023). Tuning the magnetic behavior of Sr2+ doped cobalt nickle ferrite useful for magnetic storage applications. Inorganic Chemistry Communications, 158(1):111583. https://doi.org/10.1016/j.inoche.2023.111583
Bharathi, R.V., Raju, M.K., Uppugalla, S., Raghavendra, V., Parajuli, D., Suryanarayana, B., Mulushoa, S.Y., Murali, N. and Samatha, K. (2023). Cu2+ substituted Mg-Co ferrite has improved dc electrical resistivity and magnetic properties. Inorganic Chemistry Communications, 149:110452. https://doi.org/10.1016/j.inoche.2023.110452
Fedorchuk, O.P., Plutenko, T.O., Plutenko, M.O., V'yunov, O.I., Torchyniuk, P.V., Khomenko, O.V., Lobko, Y.V., Darabut, A.M., Rodríguez, M.G., Nováková, J. and Matolínová, I. (2023). Synthesis and investigation of mixed Zn-Ni spinel nanoparticles for microwave applications. Molecular Crystals and Liquid Crystals, 768(4):1-14. https://doi.org/10.1080/15421406.2023.2272391
Gayakvad, K., Somdatta, K., Mathe, V., Dongale, T. and Patankar, K. (2023). Spinel ferrites for resistive random access memory applications. Emergent Materials, 7:103-131. https://doi.org/10.1007/s42247-023-00576-y
Gharieb, M., Ramadan, W. and Abd El-Gawad, W.M. (2023). Outstanding effect of cost-saving heavy nano-ferrites on the physico-mechanical properties, morphology, and gamma radiation shielding of hardened cement pastes. Construction and Building Materials, 409:134064. https://doi.org/10.1016/j.conbuildmat.2023.134064
Hu, W., Qin, N., Wu, G., Lin, Y., Li, S. and Bao, D. (2012). Opportunity of spinel ferrite materials in nonvolatile memory device applications based on their resistive switching performances. Journal of the American Chemical Society, 134(36):14,658-14,661. https://doi.org/10.1021/ja305681n
Jamir, M., Borgohain, C. and Borah, J.P. (2023). Influence of structure and magnetic properties of surface modified nanoparticles for hyperthermia application. Physica B: Condensed Matter, 648:414405. https://doi.org/10.1016/j.physb.2022.414405
Jeevanantham, B., Vignesh, D., Shobana, M.K., Pazhanivel, T., Thangappan, R. and Kavita, S. (2023). Theoretical and Experimental Insights of Magnesium-doped Cobalt Ferrites for Supercapacitor Applications. Electrochimica Acta, 470:143309. https://doi.org/10.1016/j.electacta.2023.143309
Kaiser, M. (2023). Effect of lanthanide and transition metal on the structure, magnetic, and electric properties of nickel ferrites. Applied Physics A, 129(12):1-12. https://doi.org/10.1007/s00339-023-07082-2
Kamran, M. and Anis-ur-Rehman, M. (2023). Influence of La3+ substitutions on structural, dielectric and electrical properties of spinel cobalt ferrite. Ceramics International, 49(4):7,017-7,029. https://doi.org/10.1016/j.ceramint.2022.10.127
Liu, B., He, C., Li, Y., Li, Z., Wang, W., Lu, Z., Wang, Z., Zhao, S., Liu, G. and Gao, X. (2023). Quasi-metallic high-entropy spinel oxides for full-spectrum solar energy harvesting. Matter, 7(1):140-157 https://doi.org/10.1016/j.matt.2023.10.020
Mondal, N.J., Sonkar, R., Boro, B., Ghosh, M.P. and Chowdhury, D. (2023). Nanocrystalline Ni-Zn spinel ferrites: size-dependent physical, photocatalytic and antioxidant properties. Nanoscale Advances, 5(20):5,460-5,475. https://doi.org/10.1039/D3NA00446E
Munawar, H.B., Hussain, A., Gouadria, S., Noreen, S., Bibi, N., Tariq, A., Tahir, M.B., Rehman, J.U., Arshad, S. and Ali, H.E. (2023). Structural, electronic, magnetic, and optical properties of MFe2O4 (M= Ni, Fe, Co) spinel ferrites: A density functional theory study. International Journal of Quantum Chemistry, 123(14):e27124. https://doi.org/10.1002/qua.27124
Munjal, S. and Khare, N., (2017). Valence change bipolar resistive switching accompanied with magnetization switching in CoFe2O4 thin film. Scientific reports, 7(1):12427. https://doi.org/10.1038/s41598-017-12579-x
Nandwana, V. and Dravid, V.P. (2023). Multicomponent magnetic spinels: From complexity of crystal chemistry to coupled magnetic resonance imaging (MRI). APL Materials, 11(5). https://doi.org/10.1063/5.0141055
Padhan, A.M., Nayak, S., Sahu, M., Jagličić, Z., Koželj, P. and Kim, H.J. (2023). Cationic redistribution induced magnetic properties of Zn2+ substituted MgFe2O4 spinel ferrite. Physica B: Condensed Matter, 668:415245. https://doi.org/10.1016/j.physb.2023.415245
Padhan, A.M., Rajaitha, P.M., Nayak, S., Hajra, S., Sahu, M., Jagličić, Z., Koželj, P. and Kim, H.J. (2023). Synthesis and application of mixed-spinel magnesioferrite: structural, vibrational, magnetic, and electrochemical sensing properties. Materials Chemistry Frontiers, 7(1):72-84. https://doi.org/10.1039/D2QM00628F
Raut, S.D., Dahotre, S.G., Singh, L.N. and Jadhav, S.N. (2021). Synthesis and Characterization of Magnetite and Cobalt Ferrite Nanoparticles by Sol-Gel Auto Combustion Technique. International Journal, 6(10):17-22. https://doi.org/10.46335/IJIES.2021.6.10.4
Salih, S.J. and Mahmood, W.M. (2023). Review on magnetic spinel ferrite (MFe2O4) nanoparticles: From synthesis to application. Heliyon, 9(6): e16601 https://doi.org/10.1016/j.heliyon.2023.e16601
Sonia, Kumari, H., Suman, Chahal, S., Devi, S., Kumar, S., Kumar, S., Kumar, P. and Kumar, A. (2023). Spinel ferrites/metal oxide nanocomposites for wastewater treatment. Applied Physics A, 129(2):91. https://doi.org/10.1007/s00339-022-06288-0
Tran, M.H., Nguyen, T.M.H. and Bark, C.W. (2024). Facile fabrication of low-defect spinel zinc ferrite oxide thin film for high-performance ultraviolet photodetector. Journal of Alloys and Compounds, 970:172422. https://doi.org/10.1016/j.jallcom.2023.172422
Zahid, M., Khan, H.M., Manzoor, M.Z., Ahmed, H.E., Akhter, T., Alshahrani, T., Imran, M. and Assiri, M.A. (2023). Optimization of structural, dielectric, and magnetic properties of nanocrystalline copper doped spinel ferrites. Materials Science and Engineering: B, 297:116739. https://doi.org/10.1016/j.mseb.2023.116739
Zheng, X.Y., Channa, S., Riddiford, L.J., Wisser, J.J., Mahalingam, K., Bowers, C.T., McConney, M.E., N' Diaye, A.T., Vailionis, A., Cogulu, E. and Ren, H., (2023). Ultra-thin lithium aluminate spinel ferrite films with perpendicular magnetic anisotropy and low damping. Nature communications, 14(1):4918. https://doi.org/10.1038/s41467-023-40733-9








