POWER FACTOR OF Bi2Te3 AND Sb2Te3 ENHANCED BY HIGH DENSITY AND HARDNESS
DOI:
https://doi.org/10.55766/sujst-2023-05-e02873Abstract
The power factor is an indicator of the performance of thermoelectric materials. Many researchers improved the thermoelectric conversion efficiency of materials by various techniques such as doping, substitution, and decreasing particle size for dense samples. We present Bi2Te3 and Sb2Te3 materials prepared by hot pressing method at 673 K for 2 h in Ar atmosphere. Bulk samples were investigated for their crystalline structure, hardness, and power factor by XRD, micro-Vickers hardness, and ZEM-3, respectively. The Seebeck coefficient, electrical resistivity, and power factor of n- Bi2Te3 and p- Bi2Te3 bulk samples were higher than literature data in the same temperature range of 325 to 475 K. The higher power factor value of Bi2Te3 and Bi2Te3 bulk samples of this study have resulted from the high density and high micro-Vickers hardness of the samples.
References
Cao, X.-H., Zhou, W.-X., Chen, C.-Y., Tang, L.-M., Long, M., and Chen., K.-Q. (2017). Excellent thermoelectric properties induced by different contact geometries in phenalenyl-based single-molecule devices. Scientific Reports, (7):10842. https://doi.org/10.1038/s41598-017-11224-x
Dharmaiah, P., Kim, H.-S., Lee, C.-H., and Hong, S.-J. (2016). Influence of powder size on thermoelectric properties of p-type 25% Bi2Te3-75% Sb2Te3 alloys fabricated using gas-atomization and spark-plasma sintering. Journal of Alloys and Compounds, 686:1-8. https://doi.org/10.1016/j.jallcom.2016.05.340
Dong, G.H., Zhu, Y.J., and Chen, L.D. (2010). Microwave-assisted rapid synthesis of Sb2Te3 nanosheets and thermoelectric properties of bulk samples prepared by spark plasma sintering. Journal of Materials Chemistry, 20:1976-1981. https://doi.org/10.1039/b915107a
Fan, X., Yang, F., Rong, Z., Cai, X., and Li, G. (2015). Characterization and thermoelectric properties of Bi0.4Sb1.6Te3 nanostructures prepared by mechanical alloying and microwave activated hot pressing. Ceramics International, 41(5):6817-6823. https://doi.org/10.1016/j.ceramint.2015.01.130
Feutelais, Y., Lendre, B., Rodier, N., and Agafonov, V. (1993). A study of phases in the bismuth-telluride system. Materials Research Bulletin., 28(6):591-596. https://doi.org/10.1016/0025-5408(93)90055-I
Hailiang, H.G., Chen, W.R., Gong, Y., Yang, M., Zeng, Y., Huang, Z., Qi, J., and Lu, S.Q. (2020). Tiecheng, Synthesis, Characterization and sintering of Li2TiO3 nanoparticles temperature solid-state reaction. Ceramics International, 46:1816-1823. https://doi.org/10.1016/
j.ceramint.2019.09.157
Hamawandi, B., Ballikaya, S., Batili, H., Roosmark, V., Orlovská, M., Yusuf, A., Johnsson, M., Szukiewicz, R., Kuchowicz, M., and Toprak, M.S. (2020). Facile solution synthesis, processing and characterization of n- and p-type binary and ternary Bi-Sb tellurides. Applied Sciences, 10(3):1178. https://doi.org/10.3390/app10031178
Hu, J., Fan, X.A., Jiang, C., Feng, B., Xiang, B.Q., Li, G., He, Z., and Li, Y. (2018). Introduction of porous structure: A feasible and promising method for improving thermoelectric performance of Bi2Te3 based bulks. Journal of Materials Science & Technology, 34(12):2458-2463. https://doi.org/10.1016/j.jmst.2018.05.010
Kalantar-Zade, K., Wlodarski, W., Li, L., Kandasamy, S., and Rosengarten, G. (2006). A thermoelectric transduces based on bismuth telluride thin films for H2 gas sensing. Journal of Rare Metal Materials and Engineering, 35(1):190-194.
Kim, Y.M., Lydia, R., Kim, J.-H., Lin, C.-C., Ahn, K., and Rhyee, J.-S. (2017). Enhancement of thermoelectric properties in liquid-phase sintered Te-excess bismuth antimony tellurides prepared by hot-press sintering.
Acta Materialia, 135:297-303. https://doi.org/10.1016/j.actamat.2017.06.036
Kumar, S., Faraz, M., and Khare, N. (2019). Enhanced thermoelectric properties of Sb2Te3-graphene nanocomposite. Mat erials Research Express, 6:085079. https://doi.org/10.1088/2053-1591/ab1d1f
Lee, G.-E., Kim, I.-H., Lim, Y.S., Seo, W.-S., Choi, B.-J., and Hwang, C.-W. (2014). Preparation and Thermoelectric properties of Bi2Te3-Bi2Se3 solid solutions. Journal of the Korean Physical Society, 64:1416-1420. https://doi.org/10.3938/jkps.64.1416
Lee, K.H., Kim, Y., Kim, D.H., Park, C.O. Kim, H.-S., and Kim, S.-I. (2021). Studies on phase formation behevior and thermoelectric transport properties of Cu-doped Bi2Te3-Bi2Se3 system. Journal of Materials Research and Technology, 15:4781-4789. https://doi.org/10.1016/j.jmrt.2021.10.049
Li, D., Sun, R.R., and Qin, X.Y. (2011). Thermoelectric properties of p-type (Bi2Te3)x(Sb2Te3)1-x prepared by spark plasma sintering. Intermetallics, 19(12):2002-2005. https://doi.org/10.1016/j.intermet.2011.07.010
Li, J.-F., Liu, W.-S., Zhao, L.-D., and Zhou, M. (2010). High-performance nanostructured thermoelectric materials. NPG Asia Materials, 2:152-158. https://doi.org/10.1038/asiamat.2010.138
Liu, R., Tan, X., Ren, G., Liu, Y., Zhou, Z., Liu, C., Lin, Y., and Nan, C. (2017). Enhanced thermoelectric performance of Te-Doped Bi2Se3−xTex bulks by self-propagating high-temperature synthesis. Crystals, 7(9):257. https://doi.org/10.3390/cryst7090257
Madavali, B., Lee, C.-H., Han, J.-G., Kim, D.H., Kim, J.T., Song, G., Lee, J.K., and Hong, S.-J. (2021). Investigation of homogeneity in microstructure and thermoelectric properties at various positions in high-thickness sintered bulks of p-type 20%Bi2Te3- 80%Sb2Te3 alloys. Journal of Materials Science: Materials in Electronics, 32:16302-16310. https://doi.org/10.1007/s10854-021-06178-w
Mukherjee, S., Femi, O.E., Chetty, R., Chattopadhyay, K., Suwas, S., and Mallik, R.C. (2018). Microstructure and Thermoelectric Properties of Cu2Te-Sb2Te3 Pseudo-binary System. Applied Surface Science, 449:805-814. https://doi.org/10.1016/j.apsusc.2017.11.198
Par ́as-Herna ́ndez, F.U., Fabi ́an-Mijangos, A., Cardona-Castro, M.A., and Alvarez-Quintana, J. (2020). Enhanced performance nanostructured thermoelectric converter for self-powering health sensors. Nano Energy, 74:104854. https://doi.org/10.1016/j.nanoen.2020.104854
Snyder, G.J. and Toberer, E.S. (2008). Complex thermoelectric materials. Nature Materials, (7):105-144. https://doi.org/10.1038/nmat2090
Xie, W., He, J., Kang, H.J., Tang, X., Zhu, S., Lever, M., Wang, S., Copley, J.R., Brown, C.M., Zhang, Q., and Tritt. T.M. (2010). Identifying the specific nanostructure responsible for the high thermoelectric performance of (Bi, Sb)2Te3 nanocomposites, Nano Letters, 10(9):3283-3289. https://doi.org/10.1021/nl100804a
Yang, J., Aizawa, T., Yamamoto, A., and Ohta, T., (2000) Thermoelectric properties of p-type (Bi2Te3)x(Sb2Te3)1-x prepared via bulk mechanical alloying and hot pressing. Journal of Alloys and Compounds, 309(1-2):225-228. https://doi.org/10.1016/S0925-388(00)01063-X
Yang, J.Y., Fan, X.A., Chen, R.G., Zhu, W., Bao, S.Q., and Duan. X.K., (2006). Consolidation and thermoelectric properties of n-type bismuth telluride based Materials by Mechanical alloying and hot pressing. Journal of Alloys and Compounds, 416(1-2):270-273. https://doi.org/10.1016/j.jallcom.2005.08.054
Yim, W.M. and Rosi, F.D. (1972). Compound tellurides and their alloys for peltier cooling: A review. Solid-State Electronics, 15(10):1121-1140. https://doi.org/10.1016/0038-1101(72)90172-4
Zhou, J., Zhu, H., Liu, T.H., Song, Q., He, R., Mao, J., Liu, Z., Ren, W., Liao, B., Singh, D.J., Ren, Z., and Chen, G. (2018). Large thermoelectric power factor from crystal symmetry protected non-bonding orbital in half-Heuslers. Nature Communications, (9):1-9. https://doi.org/10.1038/s41467-018-03866-w








