INFLUENCE OF N2 FLOW RATE ON THE PROPERTIES OF VANADIUM NITRIDE THIN FILMS DEPOSITED BY REACTIVE DC MAGNETRON SPUTTERING
DOI:
https://doi.org/10.55766/sujst-2023-04-e02237Keywords:
Reactive DC magnetron sputtering, thin film, vanadium nitrideAbstract
Vanadium nitride (VN) thin films have been deposited on silicon wafer substrates by reactive DC magnetron sputtering with varied nitrogen (N2) flow rates from 5.0 to 8.0 sccm without substrate heating. The crystallinity, morphology, and optical properties of the prepared VN films were investigated by gracing-incidence X-ray diffraction (GIXRD), field emission scanning electron microscope (FE-SEM), and UV-Vis-NIR spectrophotometer, respectively. The GIXRD pattern shows that the crystal structure of the films is consistent with the face-centered cubic VN structure. An increase in N2 led to a decrease in film thickness and sheet resistance. On the contrary, the reflectance percentage tends to increase with the increase of N2 flow rate. [Copyright information to be updated in the production process].
References
Aissani, L., Alhussein, A., Nouveau, C., Ghelani, L., and Zaabat, M. (2019). Influence of film thickness and Ar-N2 plasma gas on the structure and performance of sputtered vanadium nitride coatings. Surface and Coatings Technology, 378:124948. https://doi.org/10.1016/
j.surfcoat.2019.124948.
Chou, W.J., Yu, G.P., and Huang, J.H. (2002). Bias effect of ion-plated zirconium nitride film on Si(100). Thin Solid Films, 405(1-2):162-169. https://doi.org/10.1016/S0040-6090(01)01762-X.
Chu, X., Barnett, S.A., Wong, M.S., and Sproul, W.D. (1996). Reactive magnetron sputter deposition of polycrystalline vanadium nitride films. Journal of Vacuum Science and Technology A, 14(6):3,124-3,129. https://doi.org/10.1116/1.580180.
Gassner, G., Mayrhofer, P., Kutschej, K., Mitterer, C., and Kathrein, M. (2004). A new low friction concept for high temperatures: lubricious oxide formation on sputtered VN coatings, Tribol. Lett. 17(4):751-756. https://doi.org/10.1007/s11249-004-8083-z.
Glaser, A. Surnev, S., Netzer, F., Fateh, N., Fontalvo, G., and Mitterer, C. (2007). Oxidation of vanadium nitride and titanium nitride coatings, Surface Science, 601(4):1,153-1,159. https://doi.org/10.1016/j.susc.2006.12.010.
Guo, H., Li, B., Wang, J., Chen, W., Zhang, Z., Wang, W., and Jia, J. (2016). Microstructures, mechanical and tribological properties of VN films deposited by PLD technique. RSC Advances, 6(40):33,403-33,408. https://doi.org/10.1039/C6RA02403C.
Kim, N.Y., Son, Y.B., Oh, J.H., Hwangbo, C.K., and Park, M.C. (2000). TiNx layer as an antireflection and antistatic coating for display. Surface and Coatings Technology, 128-129:156-160. https://doi.org/10.1016/S0257-8972(00)00574-0.
Ma, C.H., Huang, J.H., and Chen, H. (2000). A study of preferred orientation of vanadium nitride and zirconium nitride coatings on silicon prepared by ion beam assisted deposition. Surface and Coatings Technology, 133-134:289-294. https://doi.org/10.1016/S0257-8972(00)00936-1.
Niyomsoan, S., Grant, W., Olson, D., and Mishra, B. (2002). Variation of color in titanium and zirconium nitride decorative thin films. Thin Solid Films, 415(1-2):187-194. https://doi.org/10.1016/S0040-6090(02)00530-8.
Parkin, I.P. and Elwin, G.S. (2001). Atmospheric pressure chemical vapour deposition of vanadium nitride and oxynitride films on glass from reaction of VCl4 with NH3. Journal of Materials Chemistry, 11:3,120-3,124. https://doi.org/10.1039/b103843p.
Signore, M.A., Rizzo, A., Valerini, D., Tapfer, L., Capodieci, L., and Cappello, A. (2010). Investigation of the physical properties of ion assisted ZrN thin films deposited by RF magnetron sputtering. Journal of Physics D: Applied Physics, 43(22):225401. https://doi.org/10.1088/0022-3727/43/22/225401.
Wang, S., Antonio, D., Yu, X., Zhang, J., Cornelius, A.L., He, D., and Zhao, Y. (2015). The hardest superconducting metal nitride. Scientific Reports, 5(1):13733. https://doi.org/10.1038/srep13733.
Wu, C.K., Huang, J.H., and Yu, G.P. (2019). Optimization of deposition processing of VN thin films using design of experiment and single-variable (nitrogen flow rate) methods. Materials Chemistry and Physics, 224:246-256. https://doi.org/10.1016/j.matchemphys.2018.12.038.








