CREATION OF A POZZOLANIC MATERIAL FROM WASTE CALCIUM HYDROXIDE AND RECYCLED GLASS POWDER
DOI:
https://doi.org/10.55766/sujst-2023-02-e02019Keywords:
Cement Replacement, Pozzolan, Recycled Glass, Waste Calcium HydroxideAbstract
The use of consumer and industrial waste as supplementary cementitious materials is one solution to the development of sustainable Portland cement. This research studied the partial replacement of cement with a pozzolanic mixture of recycled soda-lime glass powder (GP) and waste calcium hydroxide (CH). The optimal weight ratio of CH and GP was selected from five ratios between 30/70 to 70/30 (CH/GP), using thermal gravimetric analysis and X-ray diffraction. It was found that CH deficient ratios contained residual glass powder, while CH rich ratios contained residual calcium hydroxide and had undesirable carbonation of the CH. The 60/40 pozzolan was selected due to the large amount of calcium silicate hydrate (C-S-H) gel that was formed, the absence of residual GP and a minimum of excess CH. Portland cement (PC) specimens with 20 to 40 wt.% replacement by the 60/40 pozzolan were characterized for porosity and compressive strength at aging times from 3 to 28 days. The PC with 20 to 40 wt.% pozzolan had slightly increased porosity due to an increased amount of unreacted water from the batch. The porosity decreased with increased aging time. The PC with 30 wt.% pozzolan had a compressive strength equal to the reference PC, but only after 7 days or longer of aging. This was likely due to the slower reaction rate of the pozzolan. The 60/40 CH/GP pozzolan appears to be a viable partial replacement for PC when used at 30 wt.%.
References
Aïtcin, P.C. (2000). Cements of yesterday and today. Concrete of tomorrow. Cement and Concrete Research, 30:1,349-1,359. https://doi.org/10.1016/S0008-8846(00)00365-3
Appa Rao, G. (2003). Investigations of the performance of silica fume-incorporated cement pastes and mortars. Cement and Concrete Research, 33:1,765-1,770. https://doi.org/10.1016/S0008-8846(03)00171-6
Aprianti, E. (2017). A huge number of artificial waste material can be supplementary cementitious material (SCM) for concrete production - a review part II. Journal of Cleaner Production, 142:4,178-4,194. https://doi.org/10.1016/j.jclepro.2015.12.115
ASTM C311. (2005). Standard Test Methods for Sampling and Testing Fly Ash or Natural Pozzolans for Use in Portland-Cement Concrete. In: Annual Book of ASTM Standards, West Conshohocken, PA.
ASTM C642. (2006). Standard Test Method for Density, Absorption, and Voids in Hardened Concrete. In: Annual Book of ASTM Standards, West Conshohocken, PA.
ASTM C109. (2007). Standard Test Method for Compressive Strength of Hydraulic Cement Mortars. In: Annual Book of ASTM Standards, West Conshohocken, PA.
Baltakys, K., Jauberthie, R., Siauciunas, R., and Kaminskas, R. (2007). Influence of modification of SiO2 on the formation of calcium silicate hydrate. Materials Science-Poland, 25:1-8.
Beaudoin, J. and Odler, I. (2017). Hydration, Setting and Hardening of Portland Cement. In Lea's Chemistry of Cement and Concrete. 5th ed. Hewlett, P.C., and Liska, M., (eds). Elsevier, UK. p.157-249. https://doi.org/10.1016/B978-0-08-100773-0.00005-8
Consoli, N.C., Carretta, M.S., Leon, H.B., Filho, H.C.S., and Tomasi, L.F. (2019). Strength and stiffness of ground waste glass-carbide lime blends. Journal of Materials in Civil Engineering, 31:1-6. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002862
Du, H. and Tan, K.H. (2014). Waste glass powder as cement replacement in concrete. Journal of Advanced Concrete Technology, 12:468-477. https://doi.org/10.3151/jact.12.468
Gabrovšek, R., Vuk, T., and Kaučič, V. (2006). Evaluation of the hydration of Portland cement containing various carbonates by means of thermal analysis. Acta Chimica Slovenica, 53:159-165.
Holzrichter, K., Knott, A., Mertschenk, B., and Salzinger, J. (2013). Calcium Carbide. In: Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Germany. p. 1-14. https://doi.org/10.1002/14356007.a04_533.pub2
Imbabi, M.S., Carrigan, C., and McKenna, S. (2012). Trends and developments in green cement and concrete technology. International Journal of Sustainable Built Environment, 1:194-216. https://doi.org/10.1016/j.ijsbe.2013.05.001
Jiang, Y., Ling, T.C., Mo, K.M., and Shi, C. (2019). A critical review of waste glass powder - Multiple roles of utilization in cement-based materials and construction products. Journal of Environmental Management, 242:440-449. https://doi.org/10.1016/j.jenvman.2019.04.098
Kenny, M. and Oates, T. (2012). Lime and Limestone. In: Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Germany, p. 1-34.
McCarthy, M.J. and Dyer, T. (2017). Pozzolanas and Pozzolanic Materials. In Lea's Chemistry of Cement and Concrete. 5th ed. Hewlett, P.C., and Liska, M., (eds). Elsevier, UK. p. 363-467. https://doi.org/10.1016/B978-0-08-100773-0.00009-5
Mohajerani, A., Vajna, J., Cheung, T.H.H., Kurmus, H., Arulrajah, A., and Horpibulsuk, S. (2017). Practical recycling applications of crushed waste glass in construction materials: A review. Construction and Building Materials, 156:443-467. https://doi.org/10.1016/j.conbuildmat.2017.09.005
Pan, J.R., Huang, C., Kuo, J.J. and Lin, S.H. (2008). Recycling MSWI bottom and fly ash as raw materials for Portland cement. Waste Management, 28:1,113-1,118. https://doi.org/10.1016/j.wasman.2007.04.009
Papadakis, V.G., Fardis, M.N., and Vayenas, C.G. (1992). Hydration and carbonation of pozzolanic cements. ACI Materials Journal, 89:119-130. https://doi.org/10.14359/2185
Paris, J.M., Roessler, J.G., Ferraro, C.C., DeFord, H.D., and Townsend, T.G. (2016). A review of waste products utilized as supplements to Portland cement in concrete. Journal of Cleaner Production, 121:1-18. https://doi.org/10.1016/j.jclepro.2016.02.013
Rana, A., Kalla, P., Verma, H.K., and Mohnot, J.K. (2016). Recycling of dimensional stone waste on concrete: A Review. Journal of Cleaner Production, 135:312-331. https://doi.org/10.1016/j.jclepro.2016.06.126
Šavija, B. and Luković, M. (2016). Carbonation of cement paste: understanding, challenges and opportunities. Construction and Building Materials, 117:285-301. https://doi.org/10.1016/j.conbuildmat.2016.04.138
Shao, S., Lefort, T., Moras, S., and Rodriguez, D. (2000). Studies on concrete containing ground waste glass. Cement and Concrete Research, 30:91-100. https://doi.org/10.1016/S0008-8846(99)00213-6
Shelby, J.E. (2005). Compositions and Properties of Commercial Glasses. In: Introduction to Glass Science and Technology, 2nd ed. Shelby J.E. The Royal Society of Chemistry, UK. p. 262-274. https://doi.org/10.1039/9781847551160-00262
Silva, R.V., de Brito, J. and Dhir, R.K. (2018). Fresh-state performance of recycled aggregate concrete: A review. Construction and Building Materials, 178:19-21.https://doi.org/10.1016/j.conbuildmat.2018.05.149
Sprung, S. (2008). Cement. In: Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Germany, p. 1-64. https://doi.org/10.1002/14356007.a05_489.pub2
Wattanapornprom, R. and Stitmannaithum, B. (2015). Comparison of Properties of Fresh and Hardened Concrete Containing Finely Ground Glass Powder, Fly Ash, or Silica Fume. Engineering Journal, 19:35-47. https://doi.org/10.4186/ej.2015.19.3.35
Zhang, Q. and Ye, G. (2012). Dehydration kinetics of Portland cement paste at high temperature. Journal of Thermal Analysis and Calorimetry, 110:153-158. https://doi.org/10.1007/s10973-012-2303-9








