EVALUATION OF ORGANIC MATTER AND HEAVY METALS DERIVED FROM THE TANNERY SLUDGE COMPOST

Authors

  • Mahdi Haroun Department of Chemical and Environmental Engineering, Faculty of Engineering, University Putra Malaysia
  • Azni Idris Department of Chemical and Environmental Engineering, Faculty of Engineering, University Putra Malaysia
  • Syed Omar Syed Rusden Department of Land Management, Faculty of Agriculture, University Putra Malaysia

Keywords:

Tannery sludge, compost, humic matter, heavy metals

Abstract

This study focused on the characterization of organic matter (OM) and heavy metals during the composting of tannery sludge. Total concentrations of chromium, zinc, copper, lead, and cadmium in dry compost were reduced and complied with the standards of the Canadian Council of Ministers of the Environment (1995) making the compost suitable for use as a fertilizer and soil conditioner. The composting process significantly produced stable and mature compost and the concentration of the compost organic matter fractions generally decreased during the composting time while the C/N ratio exhibited a decreasing pattern throughout the composting process. Water and solution (0.01 M CaCl₂) soluble organic carbon concentrations rapidly increased to a maximum on the 20th day and declined thereafter. The changes in the humic fractions reveal that the amount of humic acids decreased during the first 20 days and increased thereafter. Reverse trends were observed in the case of fulvic acids (FA). The amounts of FA reached the maximum value on day 20 and declined thereafter.

References

Adani, F., Genevini, P.L., and Tambone, F. (1995). A new index of organic matter stability. Compost. Sci. Utilizat., 3:25-37.

AFNOR. (1993). Sols-se'diments-boues de stations d'epuration. Mise en solution des e'lements me'talliques traces (Cd, Co, Cr, Cu, Mn, Ni, Pb, Zn) par attaques acides. Association Francaise de Normalisation, La Plaine St-Denis, France, p. 139-145.

Agnew, J.M., Leonard, J.J., Feddes, J., and Feng, Y. (2003). A modified air pycnometer for compost volume and density determination. Canadian Biosystems Engineering, 45(6):27-35.

Aubert, G. (1978). Me'thodes d'Analyse des Sols. Edition CRDP, Marseilles, France.

Bernal, M.P., Navarro, A.F., Roig, A., Cegarra, J., and Garcia, D. (1996). Carbon and nitrogen transformation during composting of sweet sorghum bagasse. Biol. Fert. Soil., 22:141-148.

Bremner, J.M. (1965). Inorganic forms of nitrogen. In: Methods of Soil Analysis: Part 2, Agronomy No. 9. Black, C.A., Evans, D., White, J.L., Ensminger, L.E., and Clark, F.E. (eds). American Society of Agronomy Inc., Madison, WI, USA, p. 1,179-1,237.

Canarutto, S., Petruzzelli, G., Lubrano, L., and Guidi, G.V. (1991). How composting affects heavy metal content. BioCycle, 32:48-50.

Canadian Council of Ministers of the Environment (CCME). (1995). Proposed compost standards for Canada, 1993. Cited in the Composting Council of Canada, Composting Technologies and Practices, p. 354-390.

Chefetz, B., Hatcher, P., Hadar, Y., and Chen, Y. (1996). Chemical and biological characterization of organic matter during composting of municipal solid waste. J. Environ. Qual., 25:776-785.

Chefetz, B., Hatcher, P., Hadar, Y., and Chen, Y. (1998). Characterization of dissolved organic matter extracted from composted municipal solid waste. Soil Sci. Soc. Am. J., 62:326-332.

De Souza, E.K. (1998). Contribution à la valorisation de la bagasse par transformation biologique et chimique. Valeur agronomique des composts et proprie'te's suppressives visa-vis du champignons phytopathoge'nes Fusarium solanium. The'se de troisie'me cycle. Institut National Polytechnique de Toulouse, p. 386-392.

Drozd, J., Jamroz, E., Licznar, M., Licznar, S.E., and Weber, J. (1997). Organic matter transformation and humic indices of compost maturity stage during composting of municipal solid wastes. Proceedings of the 8th Meeting of the IHSS: The Role of Humic Substances in the Ecosystems and in Environmental Protection. Drozd, J., Gonet, S.S., Senesi, N., and Weber, J. (eds). Wrocaw, Poland 9-14 September, 1996. p. 855-863.

Dudka, S. and Muller, W.P. (1999). Accumulation of potentially toxic elements in plants and their transfer to human food chain. J. Enviro. Sci. and Health B, 34:681-708.

Eweis, J.B., Ergas, S.J., Chang, D.P.Y., and Schroeder, E.D. (1998). Bioremediation Principals. McGraw-Hill Boston, USA, 296p.

Fazrul, E.S. (2001). Utilization of sewage sludge as soil amendment. Final Report. Joint Research UPM.IWK. 50p.

Paola Castaldi, Guido Alberti b, Roberto Merella, and Pietro Melis. (2005). Study of the organic matter evolution during municipal solid waste composting aimed at identifying suitable parameters for the evaluation of compost maturity. Waste Manage, 25:209-213.

SEMARNAP. (1995). Informe tecnico. Mortandad de Aves Acuaticas en la Presa de Silva Gto. Instituto Nacional de Ecologia, Mexico, p. 67-90.

Senesi, N. (1989). Composted materials as organic fertilizers. Sci. Tot. Environ., 81/82:521-542.

Soumia, A., Mohamed, H., Georges, M., and Jean-Claude, R. (2005). Sequential extraction of heavy metals during composting of sewage sludge. Chemosphere, 59:801-810.

Garcia, C., Hernandez, T., and Costa, F. (1992). Characterization of humic acids from uncomposted and composted sewage sludge by degradative and non-degradative techniques. Bioresource Technology, 41:53-57.

Hafidi, M., Badri, W., Kaemmerer, M., and Revel, J.C. (1994). Comparaison des me'thodes d_extraction chimique et biologique pour la de'termination du phosphore assimilable. Actes Inst., Agron Vet. (Maroc), 14(3):43-48.

Hernanez-Apaolaza, L., Gasco, J.M., and Guerrero, F. (2000). Initial organic matter transformation of soil amended with composted sewage sludge. Biol. Fertil Soils, 32:421-426.

Hsu, J.H. and Lo, S.-L. (1999). Chemical and spectroscopic analysis of organic matter transformation during composting of pig manure. Environ. Pollut., 104:189-196.

Hsu, J.H. and Lo, S.L. (2001). Effect of composting on characterization and leaching of copper, manganese, and zinc from swine manure. Environ. Pollut., 114:119-127.

Iglesias-Jimenez, E., Poveda, E., Sanchez-Mart'n, M.J., and Sanchez-Camazano, M. (1997). Effect of the nature of exogenous organic matter on pesticide sorption by the soil. Arch. Environ. Contam. Toxicol., 33:117-124.

INE-DGMRAR. (1999). Manuel de procedimientos para el manejo adecuado de los residuos de la curtidurla. Direccion General de Materiales, Residuos y Actividades Riesgosas. Instituto Nacional de Ecologia. Mexico, p. 123-135.

Kononova, M. (1966). Soil Organic Matter. 2nd ed. Pergamon Oxford, UK., p. 236-385.

Lisk, D.J., Gutenmann, W.H., Rutzka, M., Kuntz, H.T., and Chu, G. (1992). Toxic materials in the soil. Arch. Environ. Contam. Toxicol., 22:190-194.

Mays, D.A. and Giordano, P.M. (1989). Land spreading municipal waste compost. BioCycle, 30(3):37-39.

Mokhtaruddin, A.M., Syed Omer, S.R., Ahmed, H.M., Siti, Z.D., Halimi, M.S., and Soumare, M., Demeyer, A., Tack, F.M.G., and Verloo, M.G. (2002). Chemical characteristics of Malian and Belgian solid waste composts. Bioresour. Technol., 81:97-101.

Soumare, M., Tack, F.M.G., and Verloo, M.G. (2003). Characterisation of Malian and Belgian solid waste composts with respect to fertility and suitability for land application. Waste Manage., 23:517-522.

Veeken, A., Nierop, K., deWilde, V., and Hamelers, B. (2000). Characterization of NaOH-extracted humic acids during composting of a biowaste. Bioresour. Technol., 72:33-41.

Zorpas, A.A., Arapoglou, D., and Panagiotis, K. (2003). Waste paper and clinoptilolite as a bulking material with dewatered anaerobically stabilized primary sewage sludge (DASPSS) for compost production. Waste Manage., 23:27-35.

Downloads

Published

2026-08-27

How to Cite

Haroun, M., Idris, A., & Syed Rusden, S. O. (2026). EVALUATION OF ORGANIC MATTER AND HEAVY METALS DERIVED FROM THE TANNERY SLUDGE COMPOST. Suranaree Journal of Science and Technology, 14(2), 129–140. retrieved from https://ph04.tci-thaijo.org/index.php/SUJST/article/view/15785

Issue

Section

Research Article

Categories