THE EFFECT OF NANO SN ADDITION TO Li4Ti5O12 NANOROD ANODE PERFORMANCE IN LITHIUM ION BATTERY APPLICATION
Keywords:
Hydrothermal, composite, Li4Ti5O12, sol-gel, activated carbon, Tin NanopowderAbstract
Research has been conducted to study the synthesis of nanorod Li4Ti5O12 (LTO) and the effect of Sn nanopowder and activated carbon addition to the battery performances. Firstly, Sol-gel process was conducted to synthesize TiO2 powder which further subjected to hydrothermal process to obtain nanorod structure. Moreover, The Li4Ti5O12 was prepared through solid-state method. Activated carbon were prepared using NaOH 1M as activation agents while Sn nanopowder was added by 10 wt%, 15 wt%, and 20wt%. The powder then characterized by SEM-EDX, XRD, and BET, and the cell performance was tested using CV, CD, and EIS. The impurities such as Rutile TiO2, and Li2TiO3 present. The highest capacity was achieved by 20 wt% Sn addition which value is 192.1 mAh/g.
References
Aifantis, K.E., Huang, T., Hackney, S.A., Sarakonsri, T., and Yu, A. (2012). Capacity fade in Sn-C nanopowder anodes due to fracture. J. Power Sourc., 197:246-252. https://doi.org/ 10.1016/j.jpowsour.2011.09.025.
Borghols, W.J.H., Wagemaker, M., Lafont, U., Kelder, E.M., and Mulder, F.M. (2009). Size effects in the Li4+xTi5O12 spinel, J. Am. Chem. Soc., 131:17,786-17,792. https:// doi.org/10.1021/ja902423e.
Cai, R., Yu, X., Liu, X., and Shao, Z. (2010). Li4Ti5O12/Sn composite anodes for lithium-ion batteries: Synthesis and electrochemical performance. J. Power Sourc., 195:8,244-8,250. https://doi.org/10.1016/j.jpowsour.2010.07.059.
Chao, S.C., Song, Y.F., Wang, C.C., Sheu, H.S., Wu, H.C., and Wu, N.L. (2011). Study on microstructural deformation of working Sn and SnSb anode particles for li-ion batteries by in situ transmission X-ray microscopy, J. Phys. Chem. C., 115:22,040-22,047. https://doi.org/10.1021/jp206829q.
Chauque, S., Oliva, F.Y., Visintin, A., Barraco, D., Leiva, E.P.M., and Cámara, O.R. (2017). Lithium titanate as anode material for lithium ion batteries: Synthesis, post-treatment and its electrochemical response, J. Electroanal. Chem., 799:142-155. https://doi.org/10.1016/j.jelechem. 2017.05.052.
Cheng, Y., Yi, Z., Wang, C., Wu, Y., and Wang, L. (2017). Controllable fabrication of C/Sn and C/SnO/Sn composites as anode materials for high-performance lithium-ion batteries. Chem. Eng. J., 330:1,035-1,043. https://doi.org/10.1016/j.cej.2017.08.066.
Hayes, W.I., Joseph, P., Mughal, M.Z., and Papakonstantinou, P. (2014). Production of reduced graphene oxide via hydrothermal reduction in an aqueous sulphuric acid suspension and its electrochemical behaviour, J. Solid State Electrochem., 19:361-380. https://doi.org/10.1007/ s10008-014-2560-6.
Huang, X., Cui, S., Chang, J., Hallac, P.B., Fell, C.R., Luo, Y., Metz, B., Jiang, J., Hurley, P.T., and Chen, J. (2015). A hierarchical tin/carbon composite as an anode for lithium-ion batteries with a long cycle life, Angew. Chemie - Int. Ed., 54:1,490-1,493. https://doi.org/10.1002/anie.201409 530
Kim, J.H. and Yoon, J.R. (2013). Preparation and characterization of Li4Ti5O12 synthesized using hydrogen titanate nanowire for hybrid super capacitor. J. Adv. Ceram., 2:285-290. https://doi.org/10.1007/s40145-013-0073-x.
Liu, R., Chen, J., Li, Z., Ding, Q., An, X., Pan, Y., Zheng, Z., Yang, M., and Fu, D. (2018). Preparation of LiFePO4/C cathode materials via a green synthesis route for lithium-ion battery applications. Materials (Basel)., 11:1-13. https://doi.org/10.3390/ma11112251.
Luo, H., Shen, L., Rui, K., Li, H., and Zhang, X. (2013). Carbon coated Li4Ti5O12 nanorods as superior anode material for high rate lithium ion batteries. J. Alloys Compd., 572:37-42. https://doi.org/10.1016/j.jallcom.2013.03.247.
Luo, Z. (2016). A practical guide to transmission electron microscopy. Volume I: Fundamentals, https://doi.org/ 10.5643/9781606507049.
Molenda, M., Chojnacka, A., Bakierska, M., and Dziembaj, R. (2014). Facile synthesis of C/Sn nanocomposite anode material for Li ion batteries, Mater. Technol., 29:A88-A92. https://doi.org/10.1179/1753555714Y.0000000192.
Ni, H., Song, W., and Fan, L. (2016). Double carbon decorated lithium titanate as anode material with high rate performance for lithium-ion batteries. Prog. Nat. Sci. Mater. Int., 26:283-288. https://doi.org/10.1016/j.pnsc. 2016.05.005.
Priyono, B., Nugraha, M.R., Syahrial, A.Z.m Faizah, A. Subhan. (2019). Optimizing performance of Li4Ti5O12 nanorod doped C@ZnO by hydrothermal synthesis as half-cell lithium-ion battery anode, IOP Conf. Ser. Mater. Sci. Eng., p. 541. https://doi.org/10.1088/1757-899X/541/1/012025.
Sandhya, C.P., John, B., and Gouri, C. (2014). Lithium titanate as anode material for lithium-ion cells: a review. Ionics (Kiel), 20:601-620. https://doi.org/10.1007/s11581-014-1113-4.
Shen, Y., Eltzholtz, J.R., and Iversen, B.B. (2013). Controlling size, crystallinity, and electrochemical performance of Li4Ti5O12 nanocrystals. RSC Adv., 5:5,023-5,029. https://doi.org/10.1021/cm402366y.
Sivashanmugam, A., Gopukumar, S., Thirunakaran, R., Nithya, C., and Prema, S. (2011). Novel Li4Ti5O12/Sn nano-composites as anode material for lithium ion batteries, Mater. Res. Bull., 46:492–500. https://doi.org/10.1016/ j.materresbull.2011.01.007.
Tocoglu, U., Cevher, O., and Akbulut, H. (2016). Cyclic performance tests of Sn/MWCNT composite lithium ion battery anodes at different temperatures. AIP Conf. Proc., 1727:20023. https://doi.org/10.1063/1.4945978.
Wang, J., Zhao, H., Yang, Q., Wang, C., Lv, P., Xia, Q. (2013). Li4Ti5O12-TiO2 composite anode material for lithium-ion batteries. J. Power Sourc., 222:196-201. https://doi.org/ 10.1016/j.jpowsour.2012.08.082.
Wang, Y., Liu, B., Li, Q., Cartmell, S., Ferrara, S., Deng, Z.D., and Xiao, J. (2015). Lithium and lithium ion batteries for applications in microelectronic devices: A review. J. Power Sourc., 286:330-345. https://doi.org/10.1016/ j.jpowsour.2015.03.164.
Wu, H.Y., Hon, M.H., Kuan, C.Y., and Leu, I.C. (2015). Hydrothermal synthesis of Li4Ti5O12 nanosheets as anode materials for lithium ion batteries. RSC Adv., 5:35,224-35,229. https://doi.org/10.1039/c5ra01351h.
Yang, S., Miao, J., Wang, Q., Lu, M., Sun, J., and Wen, T. (2016). Synthesis of graphitized carbon, nanodiamond and graphene supported Li4Ti5O12 and comparison of their electrochemical performance as anodes for lithium ion batteries, Appl. Surf. Sci., 389:428-437. https://doi.org/ 10.1016/j.apsusc.2016.07.131.
Yang, X., Huang, H., Zhang, G., Li, X., Wu, D., and Fu, R. (2015). Carbon aerogel with 3-D continuous skeleton and mesopore structure for lithium-ion batteries application. Mater. Chem. Phys., 149:657-662. https://doi.org/10.1016/ j.matchemphys.2014.11.023.
Yue, J., Badaczewski, F.M., Voepel, P., Leichtweiß, T., Mollenhauer, D., Zeier, W.G., Smarsly, B.M., Yue, J., Badaczewski, F.M., Voepel, P., Leichtweiß, T., and Mollenhauer, D. (2018). The critical role of the crystallite size in nanostructured Li4Ti5O12 anodes for lithium ion batteries. The Critical Role of the Crystallite Size in Nanostructured Li4Ti5O12 Anodes for Lithium Ion Batteries. https://doi.org/10.1021/acsami.8b05057.
Zeng, T., Hu, X., Ji, P., Peng, and Q., B. (2016). Shang, Sn embedded Li4Ti5O12/C composite as a high capacity anode material for li-ion battery. Int. J. Electrochem. Sci., 11:10,199-10,209. https://doi.org/10.20964/2016.12.58.
Zhang, Y., Hu, X., Xu, Y., and Chen, C. (2015). Preparation and electrochemical properties of Li4Ti5O12/C anode material by facile solid-state reaction, Solid State Ionics., 276:18-25. https://doi.org/10.1016/j.ssi.2015.03.033.
Zhong, Y., Li, X., Zhang, Y., Li, R., Cai, M., Sun, X. (2015). Nanostructued core-shell Sn nanowires @ CNTs with controllable thickness of CNT shells for lithium ion battery. Appl. Surf. Sci., 332:192-197. https://doi.org/ 10.1016/j.apsusc.2015.01.099.








