OPTICAL PROPERTIES OF GD2MOB2O9 TB3+ PHOSPHORS FOR FORENSIC APPLICATIONS
Keywords:
Photoluminescence, Gd2MoB2O9, phosphor, fingerprint technologyAbstract
The Gd2MoB2O9:Tb3+ phosphors were prepared by a solid-state reaction method with various concentration of Tb3+ ions as well as sintered at 900C temperature with different milling time. The photoluminescence properties were studied. The phosphors were investigated by X-ray diffraction (XRD), diffuse reflectance spectroscopy, photoluminescence, energy level scheme and decay curves studies. The phosphors were excited at a wavelength of 484 nm, the emission of the optimized phosphor at 542 nm was observed that corresponds to the 5D4→7F5 transition of Tb3+ ions. The Gd2MoB2O9:Tb3+ phosphors have potential applications in forensic science for latent fingerprint identification.
References
Ashwini, S., Prashantha, S.C., Naik, R., Naik, Y.V., Nagabhushana, H., and Jnaneshwara, D.M. (2019). Photoluminescence of a novel green emitting Bi2O3:Tb3+ nanophosphors for display, thermal sensor and visualisation of latent fingerprints. Optik., 192:162956.
Darshan, G.P., Premkumar, H.B., Nagabhushana, H., Sharma, S.C., Prashanth, S.C., and Daruka Prasad, B. (2016). Effective fingerprint recognition technique using doped yttrium aluminate nano phosphor material. J. Colloid Interface Sci., 464:206-218.
Dhanalakshmi, M., Nagabhushana, H., Sharma, S.C., Basavaraj, R.B., Darshan, G.P., and Kavyashree, D. (2018). Bio-template assisted solvothermal synthesis of broom-like BaTiO3: Nd3+ hierarchical architectures for display and forensic applications. Mater. Res. Bull., 102:235-247.
Errington, B., Lawson, G., Lewis, S.W., and Smith, G.D. (2016). Micronised Egyptian blue pigment: a novel near-infrared luminescent fingerprint dusting powder. Dyes Pigm., 132:310-315.
Kesavulu, C.R., Kim, H.J., Lee, S.W., Kaewkhao, J., Kaewnuam, E., and Wantana, N. (2017). Luminescence properties and energy transfer from Gd3+ to Tb3+ ions in gadolinium calcium silicoborate glasses for green laser application. J. Alloys Compd., 704:557-564.
Khuu, A., Chadwick, S., Spindler, X., Lam, R., Moret, S., and Roux, C. (2016). Evaluation of one-step luminescent cyanoacrylate fuming. Forensic Sci. Int., 263:126-131.
Kumar, V., Som, S., Kumar, V., Kumar, V., Ntwaeaborwa, O.M., Coetsee, E., and Swart, H.C. (2014). Tunable and white emission from ZnO:Tb3+ nanophosphors for solid state lighting applications. Chem. Eng. J., 255:541-552.
Meng, F., Zhang, X., and Seo, H.J. (2012). Optical properties of Sm3+ and Dy3+ ions in Gd2MoB2O9 host lattice. Opt. Laser Technol., 44:185-189.
Panse, V.R., Kokode, N.S., Shinde, K.N., and Dhoble, S.J. (2018). Luminescence in microcrystalline green emitting Li2Mg1−xZrO4:xTb3+ (0.1 ≤ x ≤ 2.0) phosphor. Results Phys., 8:99-103.
Park, J.Y. and Yang, H.K. (2017). Novel red-emitting Y4Zr3O12:Eu3+ nanophosphor for latent fingerprint technology. Dyes Pigm., 141:348-355.
Ruengsri, S., Insiripong, S., Sangwaranatee, N., Kim, H.J., Wantana, N., Angnanon, A., and Kaewkhao, J. (2017). Development of Dy3+-doped Gd2MoB2O9 phosphor and their luminescence behavior. Integr. Ferroelectr., 177:39-47.
Singh, V., Shinde, K.N., Singh, N., Singh, P.K., Hakeem, D.A., and Nagpure, A.S. (2018). Luminescent properties of green emitting Tb3+ doped Sr2ZnSi2O7 phosphors. Optik., 158:1,302-1,307.
Sodhi, G.S. and Kaur, J. (2001). Powder method for detecting latent fingerprints: a review. Forensic Sci. Int., 120:172-176.
Wang, W., Lei, X., Ye, Z., Zhao, N., and Yang, H. (2017). The luminescent properties and latent fingerprint identification application of AlN:Ce, Tb phosphors. J. Alloys Compd., 705:253-261.
Yang, R. and Lian, J. (2014). Studies on the development of latent fingerprints by the method of solid-medium ninhydrin. Forensic Sci. Int., 242:123-126.
Yeshodamma, S., Sunitha, D.V., Basavaraj, R.B., Darshan, G.P., Daruka Prasad, B., and Nagabhushana, H. (2019). Monovalent ions co-doped SrTiO3:Pr3+ nanostructures for the visualization of latent fingerprints and can be red component for solid state devices. J. Lumin., 208:371-387.
Zeng, C., Huang, H., Hu, Y., Miao, S., and Zhou, J. (2016). A novel blue-greenish emitting phosphor Ba3LaK (PO4)3F:Tb3+ with high thermal stability. Mater. Res. Bull., 76:62-66.








