STUDY ON THE MOLECULAR BEAM EPITAXIAL GROWTH OF SnO2 ON Si (001) SUBSTRATE

Authors

  • Dechmongkhon Kaewsuwan School of Physics, Institute of Science, Suranaree University of Technology, Nakhon Ratchasima, 30000, Thailand.
  • Thipusa Wongpinit Synchrotron Light Research Institute (Public Organization), 111 University Avenue, Muang District, Nakhon Ratchasima 30000, Thailand.
  • Chanan Euaruksakul Synchrotron Light Research Institute (Public Organization), 111 University Avenue, Muang District, Nakhon Ratchasima 30000, Thailand.
  • Narong Chanlek Synchrotron Light Research Institute (Public Organization), 111 University Avenue, Muang District, Nakhon Ratchasima 30000, Thailand.
  • Rattikorn Yimnirun School of Energy Science and Engineering, Vidyasirimedhi Institute of Science and Technology, Payupnai, Wangchan, Rayong, 21210, Thailand.
  • Saroj Rujirawat Research Network NANOTEC-SUT on Advanced Nanomaterials and Characterization, School of Physics, Institute of Science, Suranaree University of Technology, Nakhon Ratchasima, 30000, Thailand.

Keywords:

Tin dioxide, growth mechanism, LEEM, MBE, AFM

Abstract

This work reports the growth of tin dioxide (SnO2) on Si (001) substrate by molecular beam epitaxy (MBE) technique. The growth mechanism was investigated in-situ by low energy electron microscopy (LEEM). The chemical states and composition of the grown layers were confirmed by X-ray photoelectron spectroscopy (XPS). The morphology was also studied by atomic force microscopy (AFM). The result shows the morphology of grown layers as a particle of about 80 nm in diameter distributed on the substrate like the Volmer-Werber island growth mode. The result shows the possibility to create the island of tin oxide structures on the surface.

References

Bahade, S.T., Lanje, A.S., and Sharma, S.J. (2017). Synthesis of SnO2 thin film by sol-gel spin coating technique for optical and ethanol gas sensing application. IJSRST, 3(7):567-575.

Bai, G., Wang, C., Luo, M., Wang, J., Luo, Q., Luo, J., Wang, B., and Zhao, J. (2019). High-performance tin-titanium thin-film anodes prepared by magnetron co-sputtering for lithium-ion microbatteries. J. Solid State Electrochem., 23(10):2,835-2,841.

Bendjedidi, H., Attaf, A., Saidi, H., Aida, M.S., Semmari, S., Bouhdjar, A., and Benkhetta, Y. (2015). Properties of n-type SnO2 semiconductor prepared by spray ultrasonic technique for photovoltaic applications. J. Semiconduc., 36(12):123002

Chakraborty, S., and Menon, K.S. (2019). Growth and surface structural study of tin oxide films on Ag (001). Vacuum, 160:371-377.

Das, S. and Jayaraman, V. (2014). SnO2: A comprehensive review on structures and gas sensors. Prog. Mat. Sci., 66:112-255.

Franchi, S. (2013). Molecular beam epitaxy: fundamentals, historical background and future prospects. In: Molecular Beam Epitaxy, Elsevier, p. 1-46.

Fauzia, V., Yusnidar, M. N., Lalasari, L. H., Subhan, A., and Umar, A. A. (2017). High figure of merit transparent conducting Sb-doped SnO2 thin films prepared via ultrasonic spray pyrolysis. J. Alloys Comp., 720:79-85.

Han, M.A., Kim, H.J., Lee, H.C., Park, J.S., and Lee, H.N. (2019). Effects of porosity and particle size on the gas sensing properties of SnO2 films. Appl. Surf. Sci., 481:133-137.

Jain, P., Singh, S., Siddiqui, A.M., and Srivastava, A.K. (2017). Microstructural characteristics and optical performance of nano-structured thin films of tin oxide. Indian J. Pure Appl. Phys. (IJPAP), 55(6):385-393.

Javed, S., Islam, M., and Mujahid, M. (2019). Synthesis and characterization of TiO2 quantum dots by sol gel reflux condensation method. Ceramics Int., 45(2):2,676-2,679.

Kim, H.Y., Nam, J.H., George, S.M., Park, J.S., Park, B.K., Kim, G.H., Jeon, D.J., Chung, T.M., and Han, J.H. (2019). Phase-controlled SnO2 and SnO growth by atomic layer deposition using Bis(N-ethoxy-2,2-dimethyl propanamido) tin precursor. Ceramics Int. 45(4):5124-5132. https://doi. org/10.1016/j.ceramint.2018.09.263

Kwoka, M., Ottaviano, L., and Szuber, J. (2017). Comparative analysis of physico-chemical and gas sensing characteristics of two different forms of SnO2 films. Appl. Surf. Sci., 401:256-261.

Kwoka, M., Ottaviano, L., Passacantando, M., Santucci, S., Czempik, G., and Szuber, J. (2005). XPS study of the surface chemistry of L-CVD SnO2 thin films after oxidation. Thin Solid Films, 490(1):36-42.

Morresi, L. (2013). Basics of Molecular Beam Epitaxy (MBE) technique. Silicon Based Thin Film Sol. Cells, Bentham Science Publishers, p. 81-107.

Neaosuphap, S., Prabket, J., Chanlek, N., and Kobdaj, C. (2020). Physical properties of high resistivity Si, Si/SiO2 wafers and CMOS diode under 10 MeV electron irradiation. In AIP Conference Proceedings, AIP Publishing LLC., 2279(1):140001.

Nikiforov, A., Timofeev, V., Mashanov, V., Azarov, I., Loshkarev, I., Volodin, V., and Korolkov, I. (2020). Formation of SnO and SnO2 phases during the annealing of SnO (x) films obtained by molecular beam epitaxy. Appl. Surf. Sci., 512:145735.

Yang, G., Chen, C., Yao, F., Chen, Z., Zhang, Q., Zheng, X., and Ke, W. (2018). Effective carrier‐concentration tuning of SnO2 quantum dot electron‐selective layers for high‐performance planar perovskite solar cells. Adv. Mat., 30(14):1706023.

Yu, S., Li, L., Xu, D., Dong, H., and Jin, Y. (2014). Characterization of SnO2/Cu/SnO2 multilayers for high performance transparent conducting electrodes. Thin Solid Films, 562:501-505.

Yu, Y., Ma, K., Zhuang, R., Wu, K., Liao, Q., Zhong, S., Yue, H., Liu, C., Tang, S., and Liang, B. (2019). Hydroxyl-mediated formation of highly dispersed SnO2/TiO2 heterojunction via pulsed chemical vapor deposition to enhance photocatalytic activity. : Ind. Eng. Chem. Res., 58(32):14,655-14,663.

Venables, J. (2000). Introduction to surface and thin film processes. Cambridge University Press. doi:10.1017/ CBO9780511755651

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Published

2026-08-28

How to Cite

Kaewsuwan, D., Wongpinit, T., Euaruksakul, C., Chanlek, N., Yimnirun, R., & Rujirawat, S. (2026). STUDY ON THE MOLECULAR BEAM EPITAXIAL GROWTH OF SnO2 ON Si (001) SUBSTRATE. Suranaree Journal of Science and Technology, 28(6), 030072(1–5). retrieved from https://ph04.tci-thaijo.org/index.php/SUJST/article/view/15003

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Research Article