SPECTROSCOPIC PROPERTIES OF SAMARIUM DOPED POTASSIUM ALUMINIUM PHOSPHATE GLASSES
Keywords:
Samarium oxide, Judd-Ofelt analysis, luminescence and optical propertiesAbstract
In this work, potassium aluminium phosphate (K2O-Al2O3-P2O5) glasses doped with various concentrations of samarium oxide (Sm2O3) were prepared by melt-quenching technique. The structural, optical and luminescence properties of the glass samples were characterized through the molar volume, absorption and emission spectra measurements, respectively. The absorption spectra were investigated in the ultraviolet - visible light - near infrared (UV-Vis-NIR) region from 250 to 2,000 nm. The emission spectra were observed four prominent emission bands centered at 561, 597, 643, and 704 nm by excitation at 402 nm. From the Judd-Ofelt (J-O) analysis, the J-O parameters (Ω2, Ω4 and Ω6), oscillator strength (f), radiative transition possibility (AR), stimulated emission cross section ((λp)) and branching ratio (βR) were determined to investigate the local structure and bonding in the vicinity of Sm3+ ions, including quality of a glass host for using as the optical device application.
References
Carnall, W.T., Fields, P.R., and Rajnak, K. (1968). Electronic Energy Levels in the Trivalent Lanthanide Aquo Ions. I. Pr3+, Nd3+, Pm3+, Sm3+, Dy3+, Ho3+, Er3+, and Tm3+. J. Chem. Phys., 49(10): 4,424-4,442.
Cherbib, M., Krimi, S., Jazouli, A.E., Ismail, K., Lionel, M., Bertrand, R., and Mohamed, J. (2016). Structure and thermochemical study of strontium sodium phosphate glasses. J. Non-Crystalline Solids., 447:59–65.
Deopa, N., Rao, A.S., Ankur, C., Shubham, S., Abhishek, N., Jayasimhadri, M., Haranath, D., and Vijaya Prakash, G. (2018). Photoluminescence investigations on Sm3+ ions doped borate glasses for tricolor w-LEDs and lasers. Mat. Res. Bull., 100:206-212.
Linganna, K., and Jayasankar, C.K., (2012). Optical properties of Eu3+ ions in phosphate glasses. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 97:788–797.
Nanda, K., Kundu, R.S., Inder, P., Punia, R., and Kishore, N. (2016). Concentration dependence of intensity parameters and radiative properties of Sm3+ ions doped in BaO-ZnO-B2O3 glasses. J. Alloys Comp., 676:521-526.
Praveena, R., Venkatramu, V., Babu, P., and Jayasankar, C.K. (2008). Fluorescence spectroscopy of Sm3+ ions in P2O5– PbO– Nb2O5 glasses. Physica B., 403:3,527-3,534.
Rajaramakrishna, R., Knorr, B., Dierolf, V., Anavekar, R.V., and Jain, H., (2014). Spectroscopic properties of Sm3+ -doped lanthanum borogermanate glass. J. Lumines., 156:192-198.
Srinivasa Rao, Ch., and Jayasankar, C.K., (2013). Spectroscopic and radiative properties of Sm3+-doped K–Mg–Al phosphate glasses. Optics Commu., 286:204-210.
Srinivasa Rao, P., Rajyasree, Ch., Ramesh Babu, A., Vinaya Teja, P.M., and Krishna Rao, D. (2011). Effect of Bi2O3 proportion on physical, structural and electrical properties of zinc bismuth phosphate glasses. J. Non-Crystalline Solids., 357:3,585-3,591.
Vijaya, R., Venkatramu, V., Babu, P., Jayasankar, C.K., Rodríguez-Mendoza, U.R., and Lavín, V. (2013). Spectroscopic properties of Sm3+ ions in phosphate and fluorophosphate glasses. J. Non-Crystalline Solids., 365:85-92.
Vijayakumar, R., and Marimuthu, K. (2015). Concentration dependent spectroscopic properties of Sm3+ doped borophosphate glasses. J. Molec. Struc., 1092:166–175.
Wantana, N., Kaewjaeng, S., Kothan, S., Kim, H.J., and Kaewkhao, J. (2017). Energy transfer from Gd3+ to Sm3+ and luminescence characteristics of CaO–Gd2O3–SiO2–B2O3 scintillating glasses. J. Lumine., 181:382–386.
Yuliantini, L., Hidayat, R., Djamal, M., Boonin, K., Yasaka, P., Kaewnuam, E., and Kaewkhao, J. (2018). Development of Sm3+ doped ZnO-Al2O3-BaO-B2O3 glasses for optical gain medium. J. Non-Crystalline Solids., 482:86-92








