THE EFFECT OF DIFFERENT CHEMICAL FORMULAS ON THE FIRING TEMPERATURE OF R2O-RO-ZNO-R2O3-SIO2-BASED CRYSTALLINE GLAZE
Keywords:
Willemite, ceramic, firing temperature, glazeAbstract
Ceramic products with a crystalline glaze are attractive ceramic crafts. Willemite (Zn2SiO4) crystalline glaze is the most widely known due to it having crystals large enough to see with the naked eye. However, this crystalline glaze system requires a high firing temperature and the firing curve design is complicated. The present study studied the development of a glaze formula to reduce the firing temperature. Samples were fired at different firing temperatures, ranging between 1,200-1,290oC. X-ray diffraction and energy dispersive X-ray spectrometer analysis of the crystal phases after being fired at all temperatures confirmed the willemite crystals. Crystalline glaze formula 2 is a successful crystal phase at 1,250oC and the crystals can be observed with the naked eye. Therefore, crystalline glaze formula 2 is a candidate for reducing the firing temperature in crystalline glaze production.
References
Bocker, C., Funke, C., and Rüssel, C. (2017). Strengthening of a zinc silicate glass by surface crystallization. Mater. Lett., 207:41-43.
Caselli, C., Lusvardi, G., Malavasi, G., Menabue, L., and Miselli, P. (2007). Multitechnique approach to V–ZrSiO4 pigment characterization and synthesis optimization. J. Euro. Ceram. Soc., 27(2–3):1,743-1,750.
Cannio, M. and Bondioli, F. (2012). Mechanical activation of raw materials in the synthesis of Fe2O3–ZrSiO4 inclusion pigment. J. Euro. Ceram. Soc., 32(3):643-647.
Jamaludin, A.R., Kasim, S.R., and Ahmad Z.A. (2010). The effect of CaCO3 addition on the crystallization behavior of ZnO crystal glaze fired at different gloss firing and crystallization temperatures. Sci. Sinter., 42:345-355.
Karasu, B., Çakı, M., and Turan, S. (2000). The development and characterisation of zinc crystal glazes used for Amakusa-like soft porcelains. J. Euro. Ceram. Soc., 20(12):2,225-2,231.
Lee, H.S. (2013). The effect of nucleating agent on Zn2SiO4 crystal glaze. J. Korean Ceram. Soc., 50:116-121.
Pekkan, K. (2015). The thermal and microstructural behavior of a R2O–RO–(ZnO)–Al2O3–(TiO2)–SiO2 based macro-crystalline raw glaze system. Ceram. Int., 41(6):7,881-7,889.
Price, J. and Price, L. (2003). The Art of Crystalline Glazing Basic Techniques. Krause Publications Inc., Stevens Point, WI, USA, 160p.
Taylor, J.R. and Bull, A.C. (1986). Ceramics Glaze Technology. Pergamon Press, Oxford, UK, 263p.
Wang, S., Peng, C., Xiao, H., and Wu, J. (2015). Microstructural evolution and crystallization mechanism of zircon from frit glaze. J. Euro. Ceram. Soc., 35(9):2,671-2,678.
Wannagon, A., Prasanphan, S., and Sanguanpak, S. (2013). Characterization of Li–Zn–Fe crystalline phases in low temperature ceramic glaze. J. Euro. Ceram. Soc., 33(4):653-660.








