IMPROVEMENT OF MECHANICAL AND ELECTRICAL PROPERTIES OF PNN-PZT CERAMICS WITH STRONTIUM CONTENT
Keywords:
Piezoelectric, PNN-PZT, Dielectric, lowtemperature, PZTAbstract
In this research, mechanical and electrical properties of ceramics from PSNN-PZT system havebeen investigated. The ceramics with formula of Pb(1-x) Srx (Ni0.33 Nb0.67)0.5 Ti0.35 Zr0.15 O3 where x = 0.00, 0.02, 0.04, 0.06 and 0.08 were prepared by a conventional mixed-oxide method. There sults showed that with increasing Sr concentration, dielectric constant versus temperature curves become gradually broader. The degree of diffuse phase transition was enhanced with Sr dopant. The substitution of Pbion by Sr ion in the PSNN-PZT ceramics resulted in an improvement of their hardness, and fracture toughness. The maximum room temperature dielectric constant, hardness and fracture toughness were achieved from the sample with x = 0.06. This is considered as the optimized composition in this study.
References
Fuda, Y., Kumasaka, K., Katsuno, M., Sato, H., and Ino, Y., (1997). Piezoelectric Transformer for Cold Cathode Fluorescent Lamp Inverter. Jpn. J. Appl. Phys., 36:3050.
Wakiya, N., Wang,J. K., saiki,A., Shinozaki, K., and Mizutani, N., (1999). Chemical Solution Processing and Characterization of Highly Oriented (Ba, Ln) Nb2O6[Ln: La, Gd, Dy]ThinFilms.J. Eur. Ceram. Soc. 19: 1071.
Jaffe, B., Cook, W.R., and jaffe, H., (1971). Super oxidation and Electrochemical Reactions during Switching in Pb(Zr2Ti)O3 Ceramics piezoelectric ceramic, R.A.N. Publishers.
Zheng, H., Reaney, I.M., Lee, W.E., Jones, N., and Thomas, H., (2002). Surface Decomposition ofStrontium-Doped Soft PbZrO3–PbTiO3. J. Eur. Ceram. Soc. 85: 207.
Zheng, H., Reaney, I.M., Lee, W.E., Jones, N., and Thomas, H., (2001). Effects of strontium substitution in Nb-doped PZT ceramics. J. Eur. Ceram.Soc. 21:1371.
Kondo, M., Hida, M., Tsukada, M., Kurihara, K., andKamehara, N., (1997). Piezoelectric properties of Pb (Ni1/3Nb2/3)O3-Pb TiO3-PbZrO3 ceramicsnearthe MPB, J. Ceram. Soc. Jpn. 105 (8):719-721.
Kondo, M., Hida, M., Tsukada, M., Kurihara, K., and Kamehara, N., (1998). Piezoelectric properties of Pb (Ni1/3Nb2/3)O3-Pb TiO3-PbZrO3 ceramics.Jpn. J. Appl. Phys 36(9B):6043-6045.
Kondo, M., Hida, M., Tsukada, M., Kurihara, K., Kutami, M., and Kamehara, N., (1998). piezoelectric propertiesand phase transitions of Pb(Ni1/3Nb2/3)O3-PbTiO3-PbZrO3 ceramics, in: E. Colla, D. Damjanovic, N. Setter (Eds.), Proceeding of the 11th IEEE international Symposiumonthe Applications of Ferroelectrics, IEEE Ultrasonic, Ferroelectrics and Frequency Control Society, New Jersey, :311-314.
Rice, R.W., (1977). Microstructure Dependence of Mechanical Behavior of Ceramic. Treatiseon Materials Science and Technology Academic Press, New York.
Randall, C.A., Hilton, A.D., Barber, D.J., Shrout, T.R., (1993). Extrinsic contributions to the grain size dependence of relax orferroelectric Pb (Mg1/3Nb2/3)O3:Pb TiO3 ceramics.Journal of Materials Research, Volume 8, Issue4:880-884.
Xia, F., Yao, X., (2001). The role of PbO content on the dielectric and piezoelectric properties of PZN-based ceramics. (2006). J. Mater. Sci. 36:247 Bruno, J.C., Cavalheiro, A. A., Zaghete, M. A., Varela, J. A.,. Study of potassium additive on the phase formation and ferroelectric properties of 0.9PMN–0.1PT ceramics, Ceram. Inter., 32:189-194.
Tang, X.G., Chew, K.H., Chan, H.L.W., (2004). Diffuse phase transition and dielectric tenability of Ba (ZryTi1-y)O3 relaxorferroelectric ceramics. Acta. Mater., 52:5177-5183.
Yao, W., Feng, C., Li,H., Yang, Y., Yu, Y., (2003). Dielectric properties and Dielectric aging of 0.9 Pb(Mg1/3Nb2/3)O3–0.1 PbTiO3 doped with CaO. Mater. Lett., 57:2834.
AhnB.Y., Kim N.K., (2000). Effects of Barium Substitution on Perovskite formation Dielectric Properties, and Diffuseness Characteristics of Lead Zinc Niobate Ceramics, J. Am. Ceram. Soc. 83:1720-26.
Butcher, S. J. and Thomas, N.W., (1991). Ferroelectricity in the system Pb1-x Bax (Mg1/3 Nb2/3)O3. J. Phys. Chem. Solids. 52(4): 595-601.
HaertlingG. H., Zimmer W. J., (1966). Analysis of Hot-pressing Parameters for Lead Zerconate-Lead Titanate Ceramics Containingtwo atom percent Bismuth, Am. Ceram.Soc. Bull. 45: 1084-1089.
Pisitpipathsin, N., Pengpat, K., Kantha, P., Leenakul, W., Eitssayeam, S., Rujijanagul, G., Tunkasiri, T., (2010). Dielectric properties of lead-freesolid solution of Bi0.487Na0.487La0.017TiO3-Ba TiO3, PhaseTrans. 83:875-883.








