INFLUENCE OF SINTERING TEMPERATURES ON MULTIFERROIC PROPERTIES OF LEAD-FREE BNT-BT-NZF MULTIFERROIC COMPOSITE FABRICATED VIA THE SOLID-STATE COMBUSTION TECHNIQUE
BNT-BT-NZF Multiferroic Composite Fabricated via Combustion Technique
DOI:
https://doi.org/10.55766/sujst10046Keywords:
BNT-BT-NZF, Solid-state combustion, Ferromagnetic, MagnetoelectricAbstract
There has been a growing interest in multiferroics, materials that combine magnetic and electric ordering, over the past few years. This research investigates the influence of sintering temperature (1075-1175 °C for 2 hours) on multiferroic properties of 0.7(0.94Bi0.5Na0.5TiO3-0.06BaTiO3)-0.3(Ni0.7Zn0.3Fe2O4) (BNT-BT-NZF) multiferroic composites, fabricated using solid-state combustion with glycine as a fuel was investigated. The XRD patterns of all ceramics revealed the coexistence of a rhombohedral ferroelectric phase, a tetragonal ferroelectric phase, and a cubic ferromagnetic phase. The average grain size, dielectric constant (er), dielectric loss (tand), remnant polarization (Pr), and coercive field (Ec) tended to increase from 0.66 to 2.5 , 314 to 829, 0.22 to 0.51, 0.36 to 5.82 µC/cm2, and 7.05 to 26.96 kV/cm, respectively, with increase of sintering temperature. The composite ceramics exhibited peak saturation magnetization (Ms ~ 12.21 emu/g) and magnetoelectric (ME) coupling (~ 3.59 mV/cmOe) when sintered at 1150°C.
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